ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Defining the Scope of the Acid-Catalyzed Glycosidation of Glycosyl Bromides.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
10 citing papers in PubMed.
- Article
- Synthesis of 2-Deoxyglycosides with Exclusive β-Configuration Using 2-SAc Glycosyl Bromide Donors.Molecules (Basel, Switzerland) · 2025Article
- Cooperatively Catalyzed Activation of Thioglycosides That Bypasses Intermediacy of Glycosyl Halides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Expanding the scope of stereoselective α-galactosylation using glycosyl chlorides.Bioorganic & medicinal chemistry · 2022Article
- Synthesis and Glycosidation of Anomeric Halides: Evolution from Early Studies to Modern Methods of the 21st Century.Chemical reviews · 2022Review
- N-Alkylated Analogues of Indolylthio Glycosides as Glycosyl Donors with Enhanced Activation Profile.European journal of organic chemistry · 2022Article
- Bismuth(iii) triflate as a novel and efficient activator for glycosyl halides.Organic & biomolecular chemistry · 2021Article
- Stereocontrolled α-Galactosylation under Cooperative Catalysis.The Journal of organic chemistry · 2020Article
- A Highly Efficient Glycosidation of Glycosyl Chlorides by Using Cooperative Silver(I) Oxide-Triflic Acid Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Diastereoselective spACS catalysis · 2020Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Following the recent discovery that traditional silver(I) oxide-promoted glycosidations of glycosyl bromides (Koenigs-Knorr reaction) can be greatly accelerated in the presence of catalytic TMSOTf, reported herein is a dedicated study of all major aspects of this reaction. A thorough investigation of numerous silver salts and careful refinement of the reaction conditions led to an improved mechanistic understanding. This, in turn, led to a significant reduction in the amount of silver salt required for these glycosylations. The progress of this reaction can be monitored by naked eye, and the completion of the reaction can be judged by the disappearance of characteristic dark color of Ag
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Registered trials
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