ArticleAngewandte Chemie (International ed. in English)2019
Cyclic Alkenylsulfonyl Fluorides: Palladium-Catalyzed Synthesis and Functionalization of Compact Multifunctional Reagents.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Flash Communication: Sulfonyl Fluoride Activation via S-F and C-S Bond Cleavage by a Ni(0) Bis-BidentateOrganometallics · 2025Article
- Electrochemically promoted defluorinative sulfoximination and fluorosulfonylation of non-activated aryl fluorides at room temperature.Chemical science · 2025Article
- Central-to-Axial-to-Central Chirality Transfer in the Au(I)-Catalyzed Cycloisomerization of Propargyl Vinyl Ethers to Cyclopentadienes.The Journal of organic chemistry · 2025Article
- Palladium-Catalyzed Addition of Aryl Halides toJournal of the American Chemical Society · 2024Article
- Electroreductive hydroxy fluorosulfonylation of alkenes.Nature communications · 2023Article
- Photoredox-catalyzed stereo- and regioselective vicinal fluorosulfonyl-borylation of unsaturated hydrocarbons.Chemical science · 2023Article
- An efficient and mild oxidative approach from thiols to sulfonyl derivatives with DMSO/HBr.Chemical science · 2023Article
- Organomediated electrochemical fluorosulfonylation of aryl triflates via selective C-O bond cleavage.Nature communications · 2023Article
- Recent Advances of S-ACS omega · 2023Review
- Turning sulfonyl and sulfonimidoyl fluoride electrophiles into sulfur(VI) radicals for alkene ligation.Nature communications · 2023Article
- Photocatalytic conversion of aryl diazonium salts to sulfonyl fluorides.Tetrahedron · 2023Article
- Sulfur(VI) fluorides as tools in biomolecular and medicinal chemistry.Organic & biomolecular chemistry · 2023Review
- Scalable, Chemoselective Nickel Electrocatalytic Sulfinylation of Aryl Halides with SOAngewandte Chemie (International ed. in English) · 2022Article
- A practical fluorosulfonylating platform via photocatalytic imidazolium-based SONature communications · 2022Article
- Photoredox catalytic radical fluorosulfonylation of olefins enabled by a bench-stable redox-active fluorosulfonyl radical precursor.Nature communications · 2022Article
- (Hetero)aryl-SAngewandte Chemie (International ed. in English) · 2022Review
- Copper-assisted preparation of pyridinyl sulfonate esters from hydroxypyridines and sodium sulfinates.RSC advances · 2022Article
- Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides.Journal of the American Chemical Society · 2021Article
- Carbonyl 1,2-transposition through triflate-mediated α-amination.Science (New York, N.Y.) · 2021Article
- Radical-mediated vicinal addition of alkoxysulfonyl/fluorosulfonyl and trifluoromethyl groups to aryl alkyl alkynes.Chemical science · 2021Article
Corrections and comments
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3 authors.
Funding
Abstract
A series of low-molecular-weight, compact, and multifunctional cyclic alkenylsulfonyl fluorides were efficiently prepared from the corresponding alkenyl triflates. Palladium-catalyzed sulfur dioxide insertion using the surrogate reagent DABSO effects sulfinate formation, before trapping with an F electrophile delivers the sulfonyl fluorides. A broad range of functional groups are tolerated, and a correspondingly large collection of derivatization reactions are possible on the products, including substitution at sulfur, conjugate addition, and N-functionalization. Together, these attributes suggest that this method could find new applications in chemical biology.
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