ArticleAngewandte Chemie (International ed. in English)2020
A Triazole-Substituted Aryl Iodide with Omnipotent Reactivity in Enantioselective Oxidations.
Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Structural Tuning of InefficientACS omega · 2026Article
- Total Synthesis of Dactyloquinone A and Spiroetherone A via a Metal-Hydride Hydrogen Atom Transfer (MHAT) Process and a Quinol-Enedione Rearrangement.Angewandte Chemie (International ed. in English) · 2025Article
- Structure-reactivity analysis of novel hypervalent iodine reagents inFrontiers in chemistry · 2024Article
- Chiral cobalt(ii) complex-promoted asymmetricChemical science · 2023Article
- Toward a General Protocol for Catalytic Oxidative Transformations Using Electrochemically Generated Hypervalent Iodine Species.The Journal of organic chemistry · 2023Article
- Achiral organoiodine-functionalized helical polyisocyanides for multiple asymmetric dearomative oxidations.Nature communications · 2023Article
- Two-step continuous-flow synthesis of 6-membered cyclic iodonium salts via anodic oxidation.Beilstein journal of organic chemistry · 2023Article
- Structure Elucidation of In Situ Generated Chiral Hypervalent Iodine Complexes via Vibrational Circular Dichroism (VCD).Angewandte Chemie (International ed. in English) · 2022Article
- Chiral Iodotriptycenes: Synthesis and Catalytic Applications.ChemistryOpen · 2022Article
- N-Heterocyclic Iod(az)olium Salts - Potent Halogen-Bond Donors in Organocatalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- C-N Axial Chiral Hypervalent Iodine Reagents: Catalytic Stereoselective α-Oxytosylation of Ketones.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Recent discoveries on the structure of iodine(iii) reagents and their use in cross-nucleophile coupling.Chemical science · 2021Review
- An α-Cyclopropanation of Carbonyl Derivatives by Oxidative Umpolung.Angewandte Chemie (International ed. in English) · 2020Article
- Electrophilic Vinylation of Thiols under Mild and Transition Metal-Free Conditions.Angewandte Chemie (International ed. in English) · 2020Article
- Hypervalent Iodine(III)-Catalysed Enantioselective α-Acetoxylation of Ketones.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- A Triazole-Substituted Aryl Iodide with Omnipotent Reactivity in Enantioselective Oxidations.Angewandte Chemie (International ed. in English) · 2020Article
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2 authors.
Funding
Abstract
A widely applicable triazole-substituted chiral aryl iodide is described as catalyst for enantioselective oxidation reactions. The introduction of a substituent in ortho-position to the iodide is key for its high reactivity and selectivity. Besides a robust and modular synthesis, the main advantage of this catalyst is the excellent performance in a plethora of mechanistically diverse enantioselective transformations, such as spirocyclizations, phenol dearomatizations, α-oxygenations, and oxidative rearrangements. DFT-calculations of in situ generated [hydroxy(tosyloxy)iodo]arene isomers give an initial rational for the observed reactivity.
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