Evidence map›Paper›PMID 31598094›Full record

ArticleEuropean journal of organic chemistry2019

Balancing Bulkiness in Gold(I) Phosphino-triazole Catalysis.

Yiming Zhao, Matthew G Wakeling, Fernanda Meloni, Tze Jing Sum, Huy van Nguyen, Benjamin R Buckley, Paul W Davies, John S Fossey

Open access · hybridAbstract read
In one paragraph

Article in European journal of organic chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
1.0field-weighted citation impact, top 28% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 14 citations in OpenAlex.

  1. Article
  2. Balancing Bulkiness in Gold(I) Phosphino-triazole Catalysis.European journal of organic chemistry · 2019
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 1 country.

Yiming ZhaoSchool of Chemistry University of Birmingham Edgbaston B15 2TT Birmingham West Midlands UK.ORCID 0000-0003-2827-6511
Matthew G WakelingSchool of Chemistry University of Birmingham Edgbaston B15 2TT Birmingham West Midlands UK.ORCID 0000-0002-8802-7667
Fernanda MeloniSchool of Chemistry University of Birmingham Edgbaston B15 2TT Birmingham West Midlands UK.ORCID 0000-0002-0558-707X
Tze Jing SumDepartment of Chemistry Loughborough University LE11 3TU Loughborough Leicestershire UK.
Huy van NguyenSchool of Chemistry University of Birmingham Edgbaston B15 2TT Birmingham West Midlands UK.ORCID 0000-0002-3985-1510
Benjamin R BuckleyDepartment of Chemistry Loughborough University LE11 3TU Loughborough Leicestershire UK.ORCID 0000-0002-8028-0828
Paul W DaviesSchool of Chemistry University of Birmingham Edgbaston B15 2TT Birmingham West Midlands UK.ORCID 0000-0002-0340-2414
John S FosseySchool of Chemistry University of Birmingham Edgbaston B15 2TT Birmingham West Midlands UK.ORCID 0000-0002-2626-5117
University of Birmingham · GBLoughborough University · GB

Funding

Wellcome Trust
6 · The paper itself

Abstract

The syntheses of a series of 1-phenyl-5-phosphino 1,2,3-triazoles are disclosed, within which, the phosphorus atom (at the 5-position of a triazole) is appended by one, two or three triazole motifs, and the valency of the phosphorus(III) atom is completed by two, one or zero ancillary (phenyl or cyclohexyl) groups respectively. This series of phosphines was compared with tricyclohexylphosphine and triphenylphosphine to study the effect of increasing the number of triazoles appended to the central phosphorus atom from zero to three triazoles. Gold(I) chloride complexes of the synthesised ligands were prepared and analysed by techniques including single-crystal X-ray diffraction structure determination. Gold(I) complexes were also prepared from 1-(2,6-dimethoxy)-phenyl-5-dicyclohexyl-phosphino 1,2,3-triazole and 1-(2,6-dimethoxy)-phenyl-5-diphenyl-phosphino 1,2,3-triazole ligands. The crystal structures thus obtained were examined using the

Indexed as

Click chemistryGoldHomogeneous catalysisPhosphane ligandsTriazoles

Identifiers

PMID31598094
PMCPMC6774259
OpenAlexW2966561056

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.