ArticleChemistry (Weinheim an der Bergstrasse, Germany)2020
Visible-Light-Mediated Dearomatisation of Indoles and Pyrroles to Pharmaceuticals and Pesticides.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 93 citations in OpenAlex.
- Red-Light-Mediated Generation of Radicals: Applications in Organic Synthesis, Small-Molecule Activation, Polymerization, and Bio-Related Fields.Angewandte Chemie (International ed. in English) · 2025Review
- IL-6 Inhibitory Compounds from the Aerial Parts ofMolecules (Basel, Switzerland) · 2024Article
- Uranyl nitrate as a recyclable homogeneous photocatalyst for selective cross-coupling ofRSC advances · 2023Article
- Convenient Synthesis ofMolecules (Basel, Switzerland) · 2022Article
- Synthesis and Structural Study of Amidrazone Derived Pyrrole-2,5-Dione Derivatives: Potential Anti-Inflammatory Agents.Molecules (Basel, Switzerland) · 2022Article
- Photocatalytic Aerobic Dehydrogenation of N-Heterocycles with Ir(III) Photosensitizers Bearing the 2(2'-Pyridyl)benzimidazole Scaffold.Inorganic chemistry · 2022Article
- Metal-free photoredox-catalyzed direct α-oxygenation ofRSC advances · 2022Article
- Chemistry of trisindolines: natural occurrence, synthesis and bioactivity.RSC advances · 2021Review
- Light-driven selective aerobic oxidation of (iso)quinoliniums and related heterocycles.RSC advances · 2021Article
- Review
- Preparation of cyclic imides from alkene-tethered amides: application of homogeneous Cu(ii) catalytic systems.RSC advances · 2020Article
- Visible-Light-Mediated Dearomatisation of Indoles and Pyrroles to Pharmaceuticals and Pesticides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
Dearomatisation of indole derivatives to the corresponding isatin derivatives has been achieved with the aid of visible light and oxygen. It should be noted that isatin derivatives are highly important for the synthesis of pharmaceuticals and bioactive compounds. Notably, this chemistry works excellently with N-protected and protection-free indoles. Additionally, this methodology can also be applied to dearomatise pyrrole derivatives to generate cyclic imides in a single step. Later this methodology was applied for the synthesis of four pharmaceuticals and a pesticide called dianthalexin B. Detailed mechanistic studies revealed the actual role of oxygen and photocatalyst.
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Registered trials
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