ReviewAngewandte Chemie (International ed. in English)2019
Hydrogen Bonding Between Ions of Like Charge in Ionic Liquids Characterized by NMR Deuteron Quadrupole Coupling Constants-Comparison with Salt Bridges and Molecular Systems.
Review in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Ab Initio Molecular Dynamics Study of Quadrupolar Spin Relaxation in an Ionic Liquid.Journal of computational chemistry · 2026Article
- Unlocking the serine mischarging paradox and inhibiting lactyltransferase activity of AlaRS by a single-point mutation.Nucleic acids research · 2025Article
- Efficient Selective COChemSusChem · 2025Article
- Formation and Structure of Nanotubes in Imidazolium-Based Ionic Liquid Aqueous Solution.ACS omega · 2022Article
- Dissecting Noncovalent Interactions in Carboxyl-Functionalized Ionic Liquids Exhibiting Double and Single Hydrogens Bonds Between Ions of Like Charge.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- High-Temperature Quantum Tunneling and Hydrogen Bonding Rearrangements Characterize the Solid-Solid Phase Transitions in a Phosphonium-Based Protic Ionic Liquid.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Perspectives in the Computational Modeling of New Generation, Biocompatible Ionic Liquids.The journal of physical chemistry. B · 2022Review
- Thermodynamically Stable Cationic Dimers in Carboxyl-Functionalized Ionic Liquids: The Paradoxical Case of "Anti-Electrostatic" Hydrogen Bonding.Molecules (Basel, Switzerland) · 2022Article
- Cholinium amino acid-based ionic liquids.Biophysical reviews · 2021Review
- Cyclic Octamer of Hydroxyl-functionalized Cations with Net Charge Q=+8e Kinetically Stabilized by a 'Molecular Island' of Cooperative Hydrogen Bonds.Chemphyschem : a European journal of chemical physics and physical chemistry · 2020Article
- Clusters of Hydroxyl-Functionalized Cations Stabilized by Cooperative Hydrogen Bonds: The Role of Polarizability and Alkyl Chain Length.Molecules (Basel, Switzerland) · 2020Article
- Microstructural and Dynamical Heterogeneities in Ionic Liquids.Chemical reviews · 2020Article
- Hydrogen Bonding Between Ions of Like Charge in Ionic Liquids Characterized by NMR Deuteron Quadrupole Coupling Constants-Comparison with Salt Bridges and Molecular Systems.Angewandte Chemie (International ed. in English) · 2019Review
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9 authors.
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Abstract
We present deuteron quadrupole coupling constants (DQCC) for hydroxyl-functionalized ionic liquids (ILs) in the crystalline or glassy states characterizing two types of hydrogen bonding: The regular Coulomb-enhanced hydrogen bonds between cation and anion (c-a), and the unusual hydrogen bonds between cation and cation (c-c), which are present despite repulsive Coulomb forces. We measure these sensitive probes of hydrogen bonding by means of solid-state NMR spectroscopy. The DQCCs of (c-a) ion pairs and (c-c) H-bonds are compared to those of salt bridges in supramolecular complexes and those present in molecular liquids. At low temperatures, the (c-c) species successfully compete with the (c-a) ion pairs and dominate the cluster populations. Equilibrium constants obtained from molecular-dynamics (MD) simulations show van't Hoff behavior with small transition enthalpies between the differently H-bonded species. We show that cationic-cluster formation prevents these ILs from crystallizing. With cooling, the (c-c) hydrogen bonds persist, resulting in supercooling and glass formation.
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