ArticleChemical science2019
The S∴π hemibond and its competition with the S∴S hemibond in the simplest model system: infrared spectroscopy of the [benzene-(H
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Microhydration Effects on Hemibonds in [HThe journal of physical chemistry letters · 2026Article
- Isolation of kinetically-stabilised diarylchalcogenide radical cations.Communications chemistry · 2025Article
- Article
- Sulfur-centered hemi-bond radicals as active intermediates in S-DNA phosphorothioate oxidation.Nucleic acids research · 2019Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The S∴π hemibond (two-center three-electron, 2c-3e, bond) is an attractive interaction between a sulfur atom and π electrons. The S∴π hemibond is of essential importance in understanding chemistry of sulfur radical cations, and its roles in biochemistry have recently attracted much interest. In the present study, we observe the S∴π hemibond in the simplest model system in the gas phase. Infrared spectroscopy is applied to the [benzene-(H
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