ArticleThe journal of physical chemistry letters2019
Synthetic Control of Quantum Interference by Regulating Charge on a Single Atom in Heteroaromatic Molecular Junctions.
Article in The journal of physical chemistry letters, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Article
- Modulating Quantum Interference in Coronene-Based Molecular Junctions via Isoelectronic B-N Substitution at Selective Positions and Patterns.The journal of physical chemistry letters · 2025Article
- Mechanical Manipulation of Quantum Interference in Single-Molecule Junctions.Small (Weinheim an der Bergstrasse, Germany) · 2024Article
- Quantum Interference and Contact Effects in the Thermoelectric Performance of Anthracene-Based Molecules.The journal of physical chemistry. C, Nanomaterials and interfaces · 2023Article
- Optimised power harvesting by controlling the pressure applied to molecular junctions.Chemical science · 2021Article
- Molecular-scale thermoelectricity: as simple as 'ABC'.Nanoscale advances · 2020Article
- Scale-Up of Room-Temperature Constructive Quantum Interference from Single Molecules to Self-Assembled Molecular-Electronic Films.Journal of the American Chemical Society · 2020Article
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Authors and funding
10 authors.
Funding
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Abstract
A key area of activity in contemporary molecular electronics is the chemical control of conductance of molecular junctions and devices. Here we study and modify a range of pyrrolodipyridines (carbazole-like) molecular wires. We are able to change the electrical conductance and quantum interference patterns by chemically regulating the bridging nitrogen atom in the tricyclic ring system. A series of eight different N-substituted pyrrolodipyridines has been synthesized and subjected to single-molecule electrical characterization using an STM break junction. Correlations of these experimental data with theoretical calculations underline the importance of the pyrrolic nitrogen in facilitating conductance across the molecular bridge and controlling quantum interference. The large chemical modulation for the
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