ArticleAngewandte Chemie (International ed. in English)2019
Exploring London Dispersion and Solvent Interactions at Alkyl-Alkyl Interfaces Using Azobenzene Switches.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 54 citations in OpenAlex.
- London Dispersion versus Intramolecular Hydrogen Bond in Bis-Pyridines: How Accurate Is DFT for Competing Noncovalent Interactions in the Condensed Phase?Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Intramolecular London Dispersion Interactions in Single-Molecule Junctions.Journal of the American Chemical Society · 2024Article
- London Dispersion Favors Sterically Hindered Diarylthiourea Conformers in Solution.Angewandte Chemie (International ed. in English) · 2022Article
- Azobenzene-Based Solar Thermal Fuels: A Review.Nano-micro letters · 2022Review
- An Incremental System To Predict the Effect of Different London Dispersion Donors in All-meta-Substituted Azobenzenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Noncovalent CH-π and π-π Interactions in Phosphoramidite Palladium(II) Complexes with Strong Conformational Preference.Angewandte Chemie (International ed. in English) · 2021Article
- London Dispersion Interactions Rather than Steric Hindrance Determine the Enantioselectivity of the Corey-Bakshi-Shibata Reduction.Angewandte Chemie (International ed. in English) · 2021Article
- London Dispersion in Alkane Solvents.Angewandte Chemie (International ed. in English) · 2021Article
- Rational Design of Azothiophenes-Substitution Effects on the Switching Properties.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Aromatic Nanosandwich Obtained by σ-Dimerization of a Nanographenoid π-Radical.Journal of the American Chemical Society · 2020Article
- Exploring London Dispersion and Solvent Interactions at Alkyl-Alkyl Interfaces Using Azobenzene Switches.Angewandte Chemie (International ed. in English) · 2019Article
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
Interactions on the molecular level control structure as well as function. Especially interfaces between innocent alkyl groups are hardly studied although they are of great importance in larger systems. Herein, London dispersion in conjunction with solvent interactions between linear alkyl chains was examined with an azobenzene-based experimental setup. Alkyl chains in all meta positions of the azobenzene core were systematically elongated, and the change in rate for the thermally induced Z→E isomerization in n-decane was determined. The stability of the Z-isomer increased with longer chains and reached a maximum for n-butyl groups. Further elongation led to faster isomerization. The origin of the intramolecular interactions was elaborated by various techniques, including
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