Evidence map›Paper›PMID 31552696›Full record

ReviewAngewandte Chemie (International ed. in English)2019

Light-Induced Mechanistic Divergence in Gold(I) Catalysis: Revisiting the Reactivity of Diazonium Salts.

Svenja Taschinski, René Döpp, Martin Ackermann, Frank Rominger, Folkert de Vries, Maximilian F S J Menger, Matthias Rudolph, A Stephen K Hashmi, Johannes E M N Klein

Abstract readReview
In one paragraph

Review in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.

0numbers the graph read from it
0cells of the map it votes in
16citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

16 citing papers in PubMed.

  1. Photosensitizing Au(I) Catalysis With Coumarins.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Review
  7. Review
  8. Using Light to Modify the Selectivity of Transition Metal Catalysed Transformations.Angewandte Chemie (International ed. in English) · 2021
    Review
  9. Article
  10. Article
  11. Article
  12. Gold Redox Catalysis with a Selenium Cation as a Mild Oxidant.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Article
  13. Article
  14. Synthesis of Fulvene Vinyl Ethers by Gold Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Article
  15. Article
  16. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Svenja TaschinskiMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747, AG, Groningen, The Netherlands.
René DöppOrganisch-Chemisches Institut, Heidelberg University, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Martin AckermannOrganisch-Chemisches Institut, Heidelberg University, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Frank RomingerOrganisch-Chemisches Institut, Heidelberg University, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
Folkert de VriesMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747, AG, Groningen, The Netherlands.
Maximilian F S J MengerZernike Institute for Advanced Materials, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747, AG, Groningen, The Netherlands.ORCID http://orcid.org/0000-0003-1442-9601
Matthias RudolphOrganisch-Chemisches Institut, Heidelberg University, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.
A Stephen K HashmiOrganisch-Chemisches Institut, Heidelberg University, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany.ORCID http://orcid.org/0000-0002-6720-8602
Johannes E M N KleinMolecular Inorganic Chemistry, Stratingh Institute for Chemistry, Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, 9747, AG, Groningen, The Netherlands.ORCID http://orcid.org/0000-0002-1290-597X

Funding

DAAD - Deutscher Akademischer Austauschdienst (DE)Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) Germany`s Excellence Strategy - 2082/1 - 390761711.Nederlandse Organisatie voor Wetenschappelijk Onderzoek 17664Nederlandse Organisatie voor Wetenschappelijk Onderzoek 740.018014
6 · The paper itself

Abstract

In a systematic study of the Au-catalyzed reaction of o-alkynylphenols with aryldiazonium salts, we find that essentially the same reaction conditions lead to a change in mechanism when a light source is applied. If the reaction is carried out at room temperature using a Au

Indexed as

diazo compoundhomogeneous gold catalysismechanistic divergencephotochemistryvinyl gold intermediate

Identifiers

PMID31552696
PMCPMC6899485

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.