ArticleNature chemistry2019
Identification of a Frank-Kasper Z phase from shape amphiphile self-assembly.
Article in Nature chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Unravelling the intrinsic thermal conduction mechanism through phonon transport pathway engineering of long-range ordered block copolymers.Chemical science · 2026Article
- On and Off Deformability of Supramolecular Micelles in the Soft Frank-Kasper σ Phase.The journal of physical chemistry letters · 2026Article
- Accessing Frank-Kasper Phases via Blending of Architecturally Distinct and Sustainable Sugar-Based Block Co-Oligomers.Macromolecules · 2025Article
- Deactivating Symmetry Breaking of a Soft Frank-Kasper Phase via Water-Induced Conformational Ordering of a Shapeshifting Dendritic Amphiphile.ACS applied materials & interfaces · 2025Article
- Discovery of the final primitive Frank-Kasper phase of clathrate hydrates.Science advances · 2024Article
- Article
- Self-assembled soft alloy with Frank-Kasper phases beyond metals.Nature materials · 2024Article
- A soft crystalline packing with no metallic analogue.Nature materials · 2024Article
- A multiscale generative model to understand disorder in domain boundaries.Science advances · 2023Article
- Leveraging Macromolecular Isomerism for Phase Complexity in Janus Nanograins.ACS central science · 2023Article
- Topological dual and extended relations between networks of clathrate hydrates and Frank-Kasper phases.Nature communications · 2023Article
- Tetrahedral Liquid-Crystalline Networks: An A15-Like Frank-Kasper Phase Based on Rod-Packing.Angewandte Chemie (International ed. in English) · 2022Article
- Dodecagonal quasicrystals of oil-swollen ionic surfactant micelles.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Programmable two-dimensional nanocrystals assembled from POSS-containing peptoids as efficient artificial light-harvesting systems.Science advances · 2021Article
- Geometrical manipulation of complex supramolecular tessellations by hierarchical assembly of amphiphilic platinum(II) complexes.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- Article
- Discrete Block Copolymers with Diverse Architectures: Resolving Complex Spherical Phases with One Monomer Resolution.ACS central science · 2020Article
- Complex self-assembled lattices from simple polymer blends.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- Symmetry breaking in particle-forming diblock polymer/homopolymer blends.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- A cornerstone of complex crystals.Nature chemistry · 2019Article
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Authors and funding
15 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Frank-Kasper phases, a family of ordered structures formed from particles with spherical motifs, are found in a host of materials, such as metal alloys, inorganic colloids and various types of soft matter. All the experimentally observed Frank-Kasper phases can be constructed from the basic units of three fundamental structures called the A15, C15 and Z phases. The Z phase, typically observed in metal alloys, is associated with a relatively large volume ratio between its constituents, and this constraint inhibits its formation in most self-assembled single-component soft-matter systems. We have assembled a series of nanosized shape amphiphiles that comprise a triphenylene core and six polyhedral oligomeric silsesquioxane cages grafted onto it through linkers to give a variety of unconventional structures, which include the Z phase. This structure was obtained through fine tuning of the linker lengths between the core and the peripheral polyhedral oligomeric silsesquioxane cages, and exhibits a relatively large volume asymmetry between its constituent polyhedral particle motifs.
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