ReviewAngewandte Chemie (International ed. in English)2019
Geometric E→Z Isomerisation of Alkenyl Silanes by Selective Energy Transfer Catalysis: Stereodivergent Synthesis of Triarylethylenes via a Formal anti-Metallometallation.
Review in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Light-enabled intramolecular [2 + 2] cycloaddition via photoactivation of simple alkenylboronic esters.Beilstein journal of organic chemistry · 2025Article
- Photogeneration of α-Bimetalloid Radicals via Selective Activation of Multifunctional C1 Units.Journal of the American Chemical Society · 2024Article
- Iterative Dual-Metal and Energy Transfer Catalysis Enables Stereodivergence in Alkyne Difunctionalization: Carboboration as Case Study.ACS catalysis · 2023Article
- Self-assembly of benzophenone-diphenylalanine conjugate into a nanostructured photocatalyst.Chemical communications (Cambridge, England) · 2023Article
- Merging Grubbs second-generation catalyst with photocatalysis enablesChemical science · 2022Article
- Photocatalytic E→Z Contra-Thermodynamic Isomerization of Vinyl Silanes with Lewis Base.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Leveraging the n→π* Interaction in Alkene Isomerization by Selective Energy Transfer Catalysis.Angewandte Chemie (International ed. in English) · 2022Article
- Photocatalyzed Triplet Sensitization of Oximes Using Visible Light Provides a Route to Nonclassical Beckmann Rearrangement Products.Journal of the American Chemical Society · 2021Article
- IlluminatingChemical science · 2021Article
- Article
- Photocatalyzed Diastereoselective Isomerization of Cinnamyl Chlorides to Cyclopropanes.Journal of the American Chemical Society · 2020Article
- Light-Triggered Catalytic Asymmetric Allylic Benzylation with PhotogeneratedThe Journal of organic chemistry · 2020Article
- Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis.Beilstein journal of organic chemistry · 2020Review
- Geometric E→Z Isomerisation of Alkenyl Silanes by Selective Energy Transfer Catalysis: Stereodivergent Synthesis of Triarylethylenes via a Formal anti-Metallometallation.Angewandte Chemie (International ed. in English) · 2019Review
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
An efficient geometrical E→Z isomerisation of alkenyl silanes is disclosed via selective energy transfer using an inexpensive organic sensitiser. Characterised by operational simplicity, short reaction times (2 h), and broad substrate tolerance, the reaction displays high selectivity for trisubstituted systems (Z/E up to 95:5). In contrast to thermal activation, directionality results from deconjugation of the π-system in the Z-isomer due to A
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Registered trials
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