Evidence map›Paper›PMID 31537947›Full record

ArticleMacromolecules2019

Guiding the Design of Organic Photocatalyst for PET-RAFT Polymerization: Halogenated Xanthene Dyes.

Chenyu Wu, Nathaniel Corrigan, Chern-Hooi Lim, Kenward Jung, Jian Zhu, Garret Miyake, Jiangtao Xu, Cyrille Boyer

Abstract read
In one paragraph

Article in Macromolecules, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.

0numbers the graph read from it
0cells of the map it votes in
19citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

19 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
  4. Review
  5. Article
  6. Synthesis and Characterization of SeMolecules (Basel, Switzerland) · 2025
    Article
  7. Article
  8. Article
  9. Article
  10. Article
  11. Review
  12. Preparation of YPolymers · 2022
    Article
  13. Review
  14. Review
  15. Article
  16. Article
  17. Progress and Perspectives Beyond Traditional RAFT Polymerization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020
    Review
  18. Article
  19. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Chenyu WuCentre for Advanced Macromolecular Design (CAMD), School of Chemical Engineering.ORCID 0000-0002-6450-6268
Nathaniel CorriganCentre for Advanced Macromolecular Design (CAMD), School of Chemical Engineering.
Chern-Hooi LimDepartment of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872, United States.
Kenward JungCentre for Advanced Macromolecular Design (CAMD), School of Chemical Engineering.
Jian ZhuDepartment of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.ORCID 0000-0002-2704-7656
Garret MiyakeDepartment of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872, United States.ORCID 0000-0003-2451-7090
Jiangtao XuCentre for Advanced Macromolecular Design (CAMD), School of Chemical Engineering.ORCID 0000-0002-9020-7018
Cyrille BoyerCentre for Advanced Macromolecular Design (CAMD), School of Chemical Engineering.ORCID 0000-0002-4564-4702

Funding

Organic Polymerization Catalysis: Precision Macromolecules for Recognition in Biological SystemsR35GM119702 · NIGMS · UNIVERSITY OF COLORADO · PI MIYAKE, GARRET MORGAN · 2016 to 2020
$1.6M
Strongly Reducing Organic Photocatalysts as the "New Iridium" in Photoredox CatalysisF32GM122392 · NIGMS · COLORADO STATE UNIVERSITY · PI LIM, CHERN-HOOI · 2017 to 2019
$73k
NIGMS NIH HHS F32 GM122392NIGMS NIH HHS R35 GM119702
6 · The paper itself

Abstract

By examining structurally similar halogenated xanthene dyes, this study establishes a guiding principle for resolving structure-property- performance relationships in the photocontrolled PET-RAFT polymerization system (PET-RAFT: photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer). We investigated the effect of the halogen substituents on the photophysical and electrochemical properties of the xanthene dyes acting as photocatalysts and their resultant effect on the performance of PET-RAFT polymerization. Consideration of the structure- property-performance relationships allowed design of a new xanthene photocatalyst, where its photocatalytic activity (oxygen tolerance and polymerization rate) was successfully optimized for PET-RAFT polymerization. We expect that this study will serve as a theoretical framework in broadly guiding the design of high performance photocatalysts for organic photocatalysis.

Identifiers

PMID31537947
PMCPMC6752221

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.