Evidence map›Paper›PMID 31532868›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Copper-Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes.

Zheng-Li Liu, Chao Yang, Qi-Yan Xue, Meng Zhao, Cui-Cui Shan, Yun-He Xu, Teck-Peng Loh

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
  2. Review
  3. Review
  4. Review
  5. Article
  6. Article
  7. Enantioselective Copper-Catalyzed spACS central science · 2022
    Article
  8. Review
  9. Article
  10. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Zheng-Li LiuDepartment of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China.
Chao YangDepartment of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China.
Qi-Yan XueDepartment of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China.
Meng ZhaoDepartment of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China.
Cui-Cui ShanDepartment of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China.
Yun-He XuDepartment of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China.ORCID http://orcid.org/0000-0001-8817-0626
Teck-Peng LohDepartment of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, China.

Funding

Fundamental Research Funds for the Central Universities WK2060190082National Natural Science Foundation of China 21672198National Natural Science Foundation of China 21871240Natural Science Foundation of Anhui Province 1708085MB29State Key Program of National Natural Science Foundation of China 21432009
6 · The paper itself

Abstract

A copper-catalyzed silylation of propargyl dichlorides was developed to access chloro-substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro-substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol.

Indexed as

allenescopperenantioselectivitysilanessynthetic methods

Identifiers

PMID31532868
PMCPMC6899605

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.