Evidence map›Paper›PMID 31529583›Full record

ArticleAngewandte Chemie (International ed. in English)2019

A Terminal Iron Nitrilimine Complex: Accessing the Terminal Nitride through Diazo N-N Bond Cleavage.

Sadig Aghazada, Matthias Miehlich, Julian Messelberger, Frank W Heinemann, Dominik Munz, Karsten Meyer

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
2.0field-weighted citation impact, top 14% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed, 36 citations in OpenAlex.

  1. Bis(silylene)-Mediated N═N Bond Scission of Diazo Compounds.Angewandte Chemie (International ed. in English) · 2026
    Article
  2. Flash Communication: (PhOrganometallics · 2026
    Article
  3. A Lead(II) Substituted Triplet Carbene.Journal of the American Chemical Society · 2024
    Article
  4. Article
  5. Untangling ancillary ligand donationChemical science · 2024
    Article
  6. Article
  7. Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 1 institution in 1 country.

Sadig AghazadaFriedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, General and Inorganic Chemistry, Egerlandstrasse 1, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0002-7568-4481
Matthias MiehlichFriedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, General and Inorganic Chemistry, Egerlandstrasse 1, 91058, Erlangen, Germany.
Julian MesselbergerFriedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, General and Inorganic Chemistry, Egerlandstrasse 1, 91058, Erlangen, Germany.
Frank W HeinemannFriedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, General and Inorganic Chemistry, Egerlandstrasse 1, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0002-9007-8404
Dominik MunzFriedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, General and Inorganic Chemistry, Egerlandstrasse 1, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0003-3412-651X
Karsten MeyerFriedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, General and Inorganic Chemistry, Egerlandstrasse 1, 91058, Erlangen, Germany.ORCID http://orcid.org/0000-0002-7844-2998
Friedrich-Alexander-Universität Erlangen-Nürnberg · DE

Funding

Friedrich-Alexander-Universität Erlangen-NürnbergGerman-American Fulbright CommissionSchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung P2ELP2_178200Verband der Chemischen Industrie
6 · The paper itself

Abstract

A novel method for the N-N bond cleavage of trimethylsilyl diazomethane is reported for the synthesis of terminal nitride complexes. The lithium salt of trimethylsilyl diazomethane was used to generate a rare terminal nitrilimine transition metal complex with partially occupied d-orbitals. This iron complex 2 was characterized by CHN combustion analysis,

Indexed as

diazo compoundsironN-heterocyclic carbenesN−N activationterminal nitrides

Identifiers

PMID31529583
PMCPMC6916540
OpenAlexW2973972149

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.