ArticleOrganic & biomolecular chemistry2019
Effects of nano-confinement and conformational mobility on molecular imprinting of cross-linked micelles.
Article in Organic & biomolecular chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Controlling Photocatalytic Hydrodechlorination of Aryl Chlorides via Supramolecular Organization on a Molecularly Imprinted Nanoparticle.Organic letters · 2026Article
- Synthetic Mimics of Serine Proteases via Covalent Imprinting of Photo-Protected Template Molecules for Aryl Amide Hydrolysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Modeling Molecularly Imprinted Nanoparticles with LNKD: A Resource Efficient Algorithm for Polymer Cross-Linking.Journal of chemical information and modeling · 2025Article
- Advances in molecularly imprinted polymers for clinical biomarker detection (2021-2025).Mikrochimica acta · 2025Review
- Turning Enzyme Models into Model Enzymes in a Substrate-Tailored, Desolvated Active Site.ACS catalysis · 2025Article
- Rational Design and Synthesis of an Artificial Enzyme for SOrganic letters · 2024Article
- Carbonic anhydrase mimics with rationally designed active sites for fine-tuned catalytic activity and selectivity in ester hydrolysis.Catalysis science & technology · 2023Article
- Acid-Functionalized Artificial Enzymes with Tunable Selectivity for Vinyl Ether Hydrolysis.The Journal of organic chemistry · 2023Article
- Molecularly imprinted materials for glycan recognition and processing.Journal of materials chemistry. B · 2022Review
- Site-Selective Catalytic Epoxidation of Alkene with Tunable, Atomic Precision by Molecularly Imprinted Artificial Epoxidases.ACS catalysis · 2022Article
- Dynamic Tuning in Synthetic Glycosidase for Selective Hydrolysis of Alkyl and Aryl Glycosides.The Journal of organic chemistry · 2022Article
- Substrate Protection in Controlled Enzymatic Transformation of Peptides and Proteins.Chembiochem : a European journal of chemical biology · 2021Article
- Tandem Aldol Reaction from Acetal Mixtures by an Artificial Enzyme with Site-Isolated Acid and Base Functionalities.ACS applied polymer materials · 2021Article
- Sequence-Selective Protection of Peptides from Proteolysis.Angewandte Chemie (International ed. in English) · 2021Article
- Selective Hydrolysis of Aryl Esters under Acidic and Neutral Conditions by a Synthetic Aspartic Protease Mimic.ACS catalysis · 2021Article
- Tunable Artificial Enzyme-Cofactor Complex for Selective Hydrolysis of Acetals.The Journal of organic chemistry · 2021Article
- Synthetic Glycosidase Distinguishing Glycan and Glycosidic Linkage in Its Catalytic Hydrolysis.ACS catalysis · 2020Article
- pH-Controlled Nanoparticle Catalysts for Highly Selective Tandem Henry Reaction from Mixtures.ACS catalysis · 2020Article
- Synthetic glycosidases for the precise hydrolysis of oligosaccharides and polysaccharides.Chemical science · 2020Article
- Synthetic lectins for selective binding of glycoproteins in water.Chemical communications (Cambridge, England) · 2020Article
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2 authors.
Funding
Abstract
Molecular imprinting is a facile method to create guest-complementary binding sites in a cross-linked polymeric network. When performed within cross-linked micelles, the resulting molecularly imprinted nanoparticles (MINPs) exhibited an extraordinary ability to distinguish subtle structural changes in the guest, including the shift of a hydrophilic or hydrophobic group by 1 carbon and addition of a single methylene/methyl group. A high surface-cross-linking density prior to core-cross-linking was key to the high-fidelity imprinting, enhancing both the binding affinity of the imprinted micelle for the template and selectivity among structural analogues. Whereas the imprinted site closely complemented the hydrophilic surface anchoring group and rigid hydrophobic aromatic core, it was expanded significantly for a conformationally mobile small group (i.e., methoxy).
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.