ArticleAngewandte Chemie (International ed. in English)2019
Chemospecific Cyclizations of α-Carbonyl Sulfoxonium Ylides on Aryls and Heteroaryls.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Diastereoselective synthesis of substituted cyclopentanonesChemical science · 2026Article
- Direct synthesis of α-functionalized amides via heteroatom-hydrogen insertion reactions using amide-sulfoxonium ylides.Nature communications · 2024Article
- Sulfonium-based precise alkyl transposition reactions.Science advances · 2023Article
- Synthesis of the Indole-Based Inhibitors of Bacterial Cystathionine γ-Lyase NL1-NL3.Molecules (Basel, Switzerland) · 2023Article
- Enantioselective Intramolecular Iridium-Catalyzed Cyclopropanation of α-Carbonyl Sulfoxonium Ylides.Organic letters · 2022Article
- Synthesis of INature communications · 2022Article
- Rhodium-Catalyzed (4+1) Cycloaddition between Benzocyclobutenones and Styrene-Type Alkenes.Angewandte Chemie (International ed. in English) · 2022Article
- Asymmetric transformations from sulfoxonium ylides.Chemical science · 2022Review
- Regioselectivity of the SBeilstein journal of organic chemistry · 2022Article
- Deacylation-Aided C─H Alkylative Annulation through C─C Cleavage of Unstrained Ketones.Nature catalysis · 2021Article
- Enantioselective S-H Insertion Reactions of α-Carbonyl Sulfoxonium Ylides.Angewandte Chemie (International ed. in English) · 2020Article
- Ruthenium(II)-Catalyzed Homocoupling of α-Carbonyl Sulfoxonium Ylides Under Mild Conditions: Methodology Development and Mechanistic DFT Study.Frontiers in chemistry · 2020Article
- Chemospecific Cyclizations of α-Carbonyl Sulfoxonium Ylides on Aryls and Heteroaryls.Angewandte Chemie (International ed. in English) · 2019Article
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Abstract
The functionalization of aryl and heteroaryls using α-carbonyl sulfoxonium ylides without the help of a directing group has remained so far a neglected area, despite the advantageous safety profile of sulfoxonium ylides. Described herein are the cyclizations of α-carbonyl sulfoxonium ylides onto benzenes, benzofurans and N-p-toluenesulfonyl indoles in the presence of a base in HFIP, whereas pyrroles and N-methyl indoles undergo cyclization in the presence of an iridium catalyst. Significantly, these two sets of conditions are chemospecific for each groups of substrates.
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