ArticleBeilstein journal of nanotechnology2019
The impact of crystal size and temperature on the adsorption-induced flexibility of the Zr-based metal-organic framework DUT-98.
Article in Beilstein journal of nanotechnology, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
14 citing papers in PubMed.
- Defective MOFs Microreactor with Heterojunction for Selective Methane Photocatalysis via Desorption-Driven Overoxidation Suppression.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Biochar MMT ZnAl LDH composite materials derived from solid waste for heavy metal removal in artificial acid mine drainage.Scientific reports · 2025Article
- Probing the Limits of Mechanical Stability of the Mesoporous Metal-Organic Framework DUT-76(Cu) by Hydrocarbon Physisorption.ACS applied materials & interfaces · 2025Article
- Plastic Pores for Switchable and Optimized Adsorption Behaviors.ACS central science · 2025Article
- A Series of Novel 3D Coordination Polymers Based on the Quinoline-2,4-dicarboxylate Building Block and Lanthanide(III) Ions-Temperature Dependence Investigations.Molecules (Basel, Switzerland) · 2023Article
- One Atom Can Make All the Difference: Gas-Induced Phase Transformations in Bisimidazole-Linked Diamondoid Coordination Networks.Journal of the American Chemical Society · 2023Article
- Water vapour and gas induced phase transformations in an 8-fold interpenetrated diamondoid metal-organic framework.Journal of materials chemistry. A · 2023Article
- Flexible Coordination Network Exhibiting Water Vapor-Induced Reversible Switching between Closed and Open Phases.ACS applied materials & interfaces · 2022Article
- MOFs in the time domain.Nature reviews. Chemistry · 2022Review
- Efficient Removal of Chromium(VI) Anionic Species and Dye Anions from Water Using MOF-808 Materials Synthesized with the Assistance of Formic Acid.Nanomaterials (Basel, Switzerland) · 2021Article
- Beyond Frameworks: Structuring Reticular Materials across Nano-, Meso-, and Bulk Regimes.Angewandte Chemie (International ed. in English) · 2020Review
- Engineering micromechanics of soft porous crystals for negative gas adsorption.Chemical science · 2020Article
- Impact of Defects and Crystal Size on Negative Gas Adsorption in DUT-49 Analyzed byChemistry of materials : a publication of the American Chemical Society · 2020Article
- Four-dimensional metal-organic frameworks.Nature communications · 2020Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In this contribution we analyze the influence of adsorption cycling, crystal size, and temperature on the switching behavior of the flexible Zr-based metal-organic framework DUT-98. We observe a shift in the gate-opening pressure upon cycling of adsorption experiments for micrometer-sized crystals and assign this to a fragmentation of the crystals. In a series of samples, the average crystal size of DUT-98 crystals was varied from 120 µm to 50 nm and the obtained solids were characterized by X-ray diffraction, infrared spectroscopy, as well as scanning and transmission electron microscopy. We analyzed the adsorption behavior by nitrogen and water adsorption at 77 K and 298 K, respectively, and show that adsorption-induced flexibility is only observed for micrometer-sized crystals. Nanometer-sized crystals were found to exhibit reversible type I adsorption behavior upon adsorption of nitrogen and exhibit a crystal-size-dependent steep water uptake of up to 20 mmol g
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.