ArticleBeilstein journal of organic chemistry2019
α-Photooxygenation of chiral aldehydes with singlet oxygen.
Article in Beilstein journal of organic chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed, 5 citations in OpenAlex.
- Stereoselective [4+2] Cycloaddition of Singlet Oxygen to Naphthalenes Controlled by Carbohydrates.Molecules (Basel, Switzerland) · 2021Article
- Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches.Beilstein journal of organic chemistry · 2020Review
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5 authors at 2 institutions in 1 country.
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Abstract
Organocatalytic α-oxygenation of chiral aldehydes with photochemically generated singlet oxygen allows synthesizing chiral 3-substituted 1,2-diols. Stereochemical results indicate that the reaction in the presence of diarylprolinol silyl ethers is highly diastereoselective and that the configuration of a newly created stereocenter at the α-position depends predominantly on the catalyst structure. The absolute configuration of chiral 1,2-diols has been unambiguously established based on electronic circular dichroism (ECD) and TD-DFT methods.
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