Evidence map›Paper›PMID 31483634›Full record

ArticleJournal of the American Chemical Society2019

Nonsymmetrical Bis-Azine Biaryls from Chloroazines: A Strategy Using Phosphorus Ligand-Coupling.

Benjamin T Boyle, Michael C Hilton, Andrew McNally

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Article
  6. Review
  7. Article
  8. Review
  9. Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Article
  16. The 2-Pyridyl Problem: Challenging Nucleophiles in Cross-Coupling Arylations.Angewandte Chemie (International ed. in English) · 2021
    Review
  17. Phosphorus-Based Catalysis.ACS central science · 2021
    Review
  18. Article
  19. Facile Pyridine SSynlett : accounts and rapid communications in synthetic organic chemistry · 2021
    Article
  20. Late stage C-H functionalizationChemical science · 2020
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Benjamin T BoyleDepartment of Chemistry , Colorado State University , Fort Collins , Colorado 80523 , United States.ORCID 0000-0002-9360-2179
Michael C HiltonDepartment of Chemistry , Colorado State University , Fort Collins , Colorado 80523 , United States.ORCID 0000-0001-5734-3547
Andrew McNallyDepartment of Chemistry , Colorado State University , Fort Collins , Colorado 80523 , United States.ORCID 0000-0002-8651-1631

Funding

Selective Functionalization of Pyridines and Diazines via Heterocyclic Phosphonium SaltsR01GM124094 · NIGMS · COLORADO STATE UNIVERSITY · PI MCNALLY, ANDREW · 2018 to 2024
$2.0M
NIGMS NIH HHS R01 GM124094
6 · The paper itself

Abstract

Distinct approaches to synthesize bis-azine biaryls are in demand as these compounds have multiple applications in the chemical sciences and are challenging targets for metal-catalyzed cross-coupling reactions. Most approaches focus on developing new reagents as the formal nucleophilic coupling partner that can function in metal-catalyzed processes. We present an alternative approach using pyridine and diazine phosphines as nucleophilic partners and chloroazines where the heterobiaryl bond is formed via a tandem S

Indexed as

Azo CompoundsLigandsMolecular StructurePhosphorusAzo CompoundsLigandsPhosphorus

Identifiers

PMID31483634
PMCPMC6814011

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.