Evidence map›Paper›PMID 31478314›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Concise Access to the Skeleton of Protoilludane Sesquiterpenes through a Photochemical Reaction Cascade: Total Synthesis of Atlanticone C.

Andreas Zech, Christian Jandl, Thorsten Bach

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Review
  5. IntramolecularThe Journal of organic chemistry · 2025
    Article
  6. Article
  7. Article
  8. Article
  9. Total syntheses of strained polycyclic terpenes.Chemical communications (Cambridge, England) · 2022
    Review
  10. Article
  11. Article
  12. Review
  13. Ring-fused cyclobutanesChemical science · 2020
    Article
  14. Article
  15. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Andreas ZechDepartment Chemie and Catalysis Research Center (CRC), Technische Universität München, Lichtenbergstr. 4, 85747, Garching, Germany.
Christian JandlDepartment Chemie and Catalysis Research Center (CRC), Technische Universität München, Lichtenbergstr. 4, 85747, Garching, Germany.
Thorsten BachDepartment Chemie and Catalysis Research Center (CRC), Technische Universität München, Lichtenbergstr. 4, 85747, Garching, Germany.ORCID 0000-0002-1342-0202

Funding

Deutsche Forschungsgemeinschaft Ba-1372/22-1Graduate School, Technische Universität München
6 · The paper itself

Abstract

In a single photochemical operation (λ≥350 nm) an easily accessible indanone derivative was converted into a structurally complex precursor of the protoilludane sesquiterpenes. The product (60 % yield) contains all 15 carbon atoms of the skeleton in the required connectivity and was transformed into the natural product atlanticone C (9 steps, 6 % overall yield). In addition, it was shown that other protoilludanes, such as Δ

Indexed as

LightPhotochemical ProcessesMolecular StructurePolycyclic SesquiterpenesPolycyclic Sesquiterpenescarbocyclesphotochemistryreductionterpenoidstotal synthesis

Identifiers

PMID31478314
PMCPMC7687024

What OpenQuestion holds

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LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.