ArticleAngewandte Chemie (International ed. in English)2019
Site-Selective C-H Oxygenation via Aryl Sulfonium Salts.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 46 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
46 citing papers in PubMed, 234 citations in OpenAlex.
- Late-Stage Functionalization via Thianthrenation: A Reaction Enabling Rapid Preparation of Drug Beads for Chemical Pulldown.Journal of medicinal chemistry · 2026Article
- Formal Markovnikov Hydroazolation of Alkenes via Reductive Activation of Alkylthianthrenium Salts.Journal of the American Chemical Society · 2026Article
- Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross-Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Late-Stage Phenylation From [Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Thianthrenium Salts in Photochemistry.Accounts of chemical research · 2026Article
- Site-Selective C-H Sulfinamidation through Electron-Donor-Acceptor Complex Photoactivation and Radical Addition into Sulfinylamine Reagents.Organic letters · 2025Article
- Visible-Light-Mediated Synthesis of AnomericMolecules (Basel, Switzerland) · 2025Article
- Standardized Approach for Diversification of Complex Small Molecules via Aryl Thianthrenium Salts.Journal of the American Chemical Society · 2025Article
- Meta-Dimethylation of Arenes via Catellani Reaction from Aryl Thianthrenium Salts.Angewandte Chemie (International ed. in English) · 2025Article
- Stabilized Carbon Radical-Mediated Assembly of Arylthianthrenium Salts, Alkenes and Amino Acid/Peptide Derivatives.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Metallaphotoredox deuteroalkylation utilizing thianthrenium salts.Nature communications · 2024Article
- Stereospecific syn-dihalogenations and regiodivergent syn-interhalogenation of alkenes via vicinal double electrophilic activation strategy.Nature communications · 2024Article
- Direct C-H Hydroxylation ofJournal of the American Chemical Society · 2024Article
- A Paternò-Büchi Reaction of Aromatics with Quinones under Visible Light Irradiation.Molecules (Basel, Switzerland) · 2024Article
- Synthesis of meta-carbonyl phenols and anilines.Nature communications · 2024Article
- CspChemical science · 2024Review
- Late-stage modification of bioactive compounds: Improving druggability through efficient molecular editing.Acta pharmaceutica Sinica. B · 2024Review
- Hydroxylation of Aryl Sulfonium Salts for Phenol Synthesis under Mild Reaction Conditions.Molecules (Basel, Switzerland) · 2024Article
- Site-selective and metal-free C-H phosphonation of arenesRSC advances · 2023Article
- Site-selective carbonylation of arenesChemical science · 2023Article
Corrections and comments
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Authors and funding
7 authors at 1 institution in 1 country.
Funding
Abstract
Herein, we report a two-step process forming arene C-O bonds in excellent site-selectivity at a late-stage. The C-O bond formation is achieved by selective introduction of a thianthrenium group, which is then converted into C-O bonds using photoredox chemistry. Electron-rich, -poor and -neutral arenes as well as complex drug-like small molecules are successfully transformed into both phenols and various ethers. The sequence differs conceptually from all previous arene oxygenation reactions in that oxygen functionality can be incorporated into complex small molecules at a late stage site-selectively, which has not been shown via aryl halides.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.