Evidence map›Paper›PMID 31469942›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates.

Daniel E Diaz, David A Quist, Austin E Herzog, Andrew W Schaefer, Ioannis Kipouros, Mayukh Bhadra, Edward I Solomon, Kenneth D Karlin

Open access · greenAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.

0numbers the graph read from it
0cells of the map it votes in
19citing papers in PubMed
1.6field-weighted citation impact, top 17% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

19 citing papers in PubMed, 46 citations in OpenAlex.

  1. Article
  2. Review
  3. Article
  4. Article
  5. Article
  6. Article
  7. Review
  8. Article
  9. Mimicking the Reactivity of LPMOs with a Mononuclear Cu Complex.European journal of inorganic chemistry · 2024
    Article
  10. Article
  11. Article
  12. Ligand-Copper(I) Primary OAccounts of chemical research · 2023
    Article
  13. Fenton-like Chemistry by a Copper(I) Complex and HJournal of the American Chemical Society · 2023
    Article
  14. Article
  15. Article
  16. Evidence for H-bonding interactions to the μ-ηChemical communications (Cambridge, England) · 2022
    Article
  17. Article
  18. Article
  19. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 1 country.

Daniel E DiazChemistry Department, Johns Hopkins University, Baltimore, MD, 21218, USA.ORCID 0000-0001-8202-920X
David A QuistChemistry Department, Johns Hopkins University, Baltimore, MD, 21218, USA.ORCID 0000-0002-6996-5586
Austin E HerzogChemistry Department, Johns Hopkins University, Baltimore, MD, 21218, USA.ORCID 0000-0002-4584-7163
Andrew W SchaeferChemistry Department, Stanford University, Stanford, CA, 94305, USA.ORCID 0000-0001-6565-920X
Ioannis KipourosChemistry Department, Stanford University, Stanford, CA, 94305, USA.
Mayukh BhadraChemistry Department, Johns Hopkins University, Baltimore, MD, 21218, USA.ORCID 0000-0002-4758-1610
Edward I SolomonChemistry Department, Stanford University, Stanford, CA, 94305, USA.ORCID 0000-0003-0291-3199
Kenneth D KarlinChemistry Department, Johns Hopkins University, Baltimore, MD, 21218, USA.ORCID 0000-0002-5675-7040
Johns Hopkins University · USStanford University · US

Funding

Structure/Function Correlations Over Copper EnzymesR01DK031450 · NIDDK · STANFORD UNIVERSITY · PI EDWARD I SOLOMON · 1986 to 2026
$8.7M
NEW COPPER(I) CHEMISTRY-MODELS FOR METALLOPROTEINSR01GM028962 · NIGMS · STATE UNIVERSITY OF NEW YORK AT ALBANY · PI KARLIN, KENNETH D. · 1985 to 2020
$6.7M
SPECTROSCOPIC STUDIES OF COPPER CLUSTERS IN PROTEINSR37DK031450 · NIDDK · STANFORD UNIVERSITY · PI SOLOMON, EDWARD I · 1994 to 2011
$5.7M
BIOINORGANIC COPPER COORDINATION CHEMISTRYR37GM028962 · NIGMS · JOHNS HOPKINS UNIVERSITY · PI KARLIN, KENNETH D. · 1993 to 2002
$882k
NIDDK NIH HHS R01 DK031450NIDDK NIH HHS R37 DK031450NIGMS NIH HHS R01 GM028962NIGMS NIH HHS R37 GM028962
6 · The paper itself

Abstract

The dioxygen reactivity of a series of TMPA-based copper(I) complexes (TMPA=tris(2-pyridylmethyl)amine), with and without secondary-coordination-sphere hydrogen-bonding moieties, was studied at -135 °C in 2-methyltetrahydrofuran (MeTHF). Kinetic stabilization of the H-bonded [(

Indexed as

BiocatalysisCarbonCold TemperatureCoordination ComplexesCopperGalactose OxidaseHydrogen BondingModels, MolecularMolecular StructureNitrogenPhenolsProtein BindingPyridinesStructure-Activity RelationshipSuperoxidesCarbonCoordination ComplexesCoppercupric oxideGalactose OxidaseNitrogenPhenolsPyridinesSuperoxidestris(2-pyridylmethyl)aminecopper monooxygenasescupric superoxidedioxygen reductionH-atom transferhydrogen bonding

Identifiers

PMID31469942
PMCPMC6878127
OpenAlexW2970819209

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.