ArticleChemistry (Weinheim an der Bergstrasse, Germany)2019
An Experimental Acidity Scale for Intramolecularly Stabilized Silyl Lewis Acids.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed, 39 citations in OpenAlex.
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- Origin of theJournal of the American Chemical Society · 2026Article
- Isolation of halogen-substituted silylium ions.Nature chemistry · 2025Article
- Hexaphenyl-1,2-Diphosphonium Dication [PhJournal of the American Chemical Society · 2025Article
- Crystal structures of the Lewis acid-base adducts {[(CActa crystallographica. Section E, Crystallographic communications · 2022Article
- Hydrogen-Bridged Oligosilanylsilyl Mono- and Oligosilanylsilyl Dications.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Geometrically Constrained Cationic Low-Coordinate Tetrylenes: Highly Lewis Acidic σ-Donor Ligands in Catalytic Systems.Angewandte Chemie (International ed. in English) · 2022Article
- What Distinguishes the Strength and the Effect of a Lewis Acid: Analysis of the Gutmann-Beckett Method.Angewandte Chemie (International ed. in English) · 2022Article
- Silicon Tetrakis(trifluoromethanesulfonate): A Simple Neutral Silane Acting as a Soft and Hard Lewis Superacid.Angewandte Chemie (International ed. in English) · 2021Article
- Multidimensional Lewis Acidity: A Consistent Data Set of Chloride, Hydride, Methide, Water and Ammonia Affinities for 183 p-Block Element Lewis Acids.Chemphyschem : a European journal of chemical physics and physical chemistry · 2021Article
- Lewis Acidic Boranes, Lewis Bases, and Equilibrium Constants: A Reliable Scaffold for a Quantitative Lewis Acidity/Basicity Scale.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Intramolecular Halo Stabilization of Silyl Cations-Silylated Halonium- and Bis-Halo-Substituted Siliconium Borates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Easy Access to Enantiomerically Pure Heterocyclic Silicon-Chiral Phosphonium Cations and the Matched/Mismatched Case of Dihydrogen Release.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Chiral Chalcogenyl-Substituted Naphthyl- and Acenaphthyl-Silanes and Their Cations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- An Extensive Set of Accurate Fluoride Ion Affinities for p-Block Element Lewis Acids and Basic Design Principles for Strong Fluoride Ion Acceptors.Chemphyschem : a European journal of chemical physics and physical chemistry · 2020Article
- An Experimental Acidity Scale for Intramolecularly Stabilized Silyl Lewis Acids.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
Abstract
A new NMR-based Lewis acidity scale is suggested and its application is demonstrated for a family of silyl Lewis acids. The reaction of p-fluorobenzonitrile (FBN) with silyl cations that are internally stabilized by interaction with a remote chalcogenyl or halogen donor yields silylated nitrilium ions with the silicon atom in a trigonal bipyramidal coordination environment. The
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.