ArticleAngewandte Chemie (International ed. in English)2019
Combined Photoredox/Enzymatic C-H Benzylic Hydroxylations.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. It has been retracted, and should not be counted. Cited by 15 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
15 citing papers in PubMed, 60 citations in OpenAlex.
- Advanced Electroanalysis for Electrosynthesis.ACS organic & inorganic Au · 2024Review
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- Photobiocatalytic Strategies for Organic Synthesis.Chemical reviews · 2023Review
- A Horseradish Peroxidase-Mediator System for Benzylic C-H Activation.ACS catalysis · 2022Article
- Aroyl Fluorides as Bifunctional Reagents for Dearomatizing Fluoroaroylation of Benzofurans.Journal of the American Chemical Society · 2022Article
- Deracemization of 1-phenylethanols in a one-pot process combining Mn-driven oxidation with enzymatic reduction utilizing a compartmentalization technique.RSC advances · 2022Article
- Photoredox-Catalyzed C-H Functionalization Reactions.Chemical reviews · 2022Review
- Metal-free, visible-light induced enantioselective three-component dicarbofunctionalization and oxytrifluoromethylation of enaminesChemical science · 2022Article
- Chromoselective Photocatalysis Enables Stereocomplementary Biocatalytic Pathways.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2021Article
- Chromoselective Photocatalysis Enables Stereocomplementary Biocatalytic Pathways*.Angewandte Chemie (International ed. in English) · 2021Article
- Benzylic C(spChemical science · 2021Article
- Benzylic Methylene Functionalizations of Diarylmethanes.Chemistry, an Asian journal · 2020Review
- Radical coupling ofGreen synthesis and catalysis · 2020Article
- A Sequential Umpolung/Enzymatic Dynamic Kinetic Resolution Strategy for the Synthesis of γ-Lactones.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Recent developments in enantioselective photocatalysis.Beilstein journal of organic chemistry · 2020Review
Corrections and comments
- Retraction · 2023-08-24Falsification/Fabrication of Data · Unreliable Data · Unreliable Results and/or Conclusions ·
- Retracted
Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
Chemical transformations that install heteroatoms into C-H bonds are of significant interest because they streamline the construction of value-added small molecules. Direct C-H oxyfunctionalization, or the one step conversion of a C-H bond to a C-O bond, could be a highly enabling transformation due to the prevalence of the resulting enantioenriched alcohols in pharmaceuticals and natural products,. Here we report a single-flask photoredox/enzymatic process for direct C-H hydroxylation that proceeds with broad reactivity, chemoselectivity and enantioselectivity. This unified strategy advances general photoredox and enzymatic catalysis synergy and enables chemoenzymatic processes for powerful and selective oxidative transformations.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.