ArticleMolecules (Basel, Switzerland)2019
Effect of Ionic Composition on Physicochemical Properties of Mono-Ether Functional Ionic Liquids.
Article in Molecules (Basel, Switzerland), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Influence of Ether-Functionalized Pyrrolidinium Ionic Liquids on Properties and LiThe journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Low-temperature heat capacity and the thermodynamic functions of a novel ether-based ionic liquid 1-(2-ethoxyethyl)-3-ethylimidazolium thiocyanate.RSC advances · 2024Article
- Ionic liquids as the effective technology for enhancing transdermal drug delivery: Design principles, roles, mechanisms, and future challenges.Asian journal of pharmaceutical sciences · 2024Review
- Applications of Ionic Liquids in Carboxylic Acids Separation.Membranes · 2022Review
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Authors and funding
9 authors.
Funding
Abstract
Tunable properties prompt the development of different "tailor-made" functional ionic liquids (FILs) for specific tasks. FILs with an ether group are good solvents for many organic compounds and enzymatic reactions. However, ionic composition influences the solubility by affecting the physiochemical properties of these FILs. To address the structure effect, a series of novel FILs with a mono-ether group (ME) based on imidazole were prepared through cationic functionalization and anionic exchange reactions, and characterized by NMR, mass spectroscopy, and Thermogravimetric analysis (TGA). The effect of ionic composition (cationic structure and anions) on density, viscosity, ionic conductivity, electrochemical window, and thermal properties of these ME-FILs were systematically investigated. In general, the viscosity and heat capacity increases with the bigger cationic volume of ME-FILs; in particular, the 2-alkyl substitution of imidazolium enhances the viscosity remarkably, whereas the density and conductivity decrease on the condition of the same [NTf
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