ArticleAngewandte Chemie (International ed. in English)2019
Acyl-Directed ortho-Borylation of Anilines and C7 Borylation of Indoles using just BBr
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 20 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
20 citing papers in PubMed, 116 citations in OpenAlex.
- Stable BFAngewandte Chemie (International ed. in English) · 2026Article
- BXChemistry, an Asian journal · 2026Review
- Computational tools for the prediction of site- and regioselectivity of organic reactions.Chemical science · 2025Review
- Site Selective Boron DirectedOrganic letters · 2025Article
- Article
- Boron-mediated one-pot access to salicylaldehydesRSC advances · 2024Article
- Borylation-Reduction-Borylation for the Formation of 1,4-Azaborines.Organic letters · 2023Article
- RegioselectiveChemical science · 2023Article
- Borylation directed borylation ofChemical science · 2023Article
- Metal-free C-H Borylation and Hydroboration of Indoles.ACS omega · 2023Review
- Amides as modifiable directing groups in electrophilic borylation.Chemical science · 2023Article
- Two Directing Groups Used for Metal CatalysedEuropean journal of organic chemistry · 2022Article
- Borylation Directed Borylation of Indoles Using Pyrazabole Electrophiles: A One-Pot Route to C7-Borylated-Indolines.Angewandte Chemie (International ed. in English) · 2022Article
- Steric Shielding Effects Induced by Intramolecular C-H⋯O Hydrogen Bonding: Remote Borylation Directed by Bpin Groups.ACS catalysis · 2022Article
- Enhanced N-directed electrophilic C-H borylation generates BN-[5]- and [6]helicenes with improved photophysical properties.Chemical science · 2022Article
- Pyrimidine-directed metal-free C-H borylation of 2-pyrimidylanilines: a useful process for tetra-coordinated triarylborane synthesis.Chemical science · 2021Article
- Ligand-free iridium-catalyzed regioselective C-H borylation of indoles.RSC advances · 2021Article
- Phosphorus(III)-assisted regioselective C-H silylation of heteroarenes.Nature communications · 2021Article
- Metal-Free C-H Borylation of N-Heteroarenes by Boron Trifluoride.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Acyl-Directed ortho-Borylation of Anilines and C7 Borylation of Indoles using just BBrAngewandte Chemie (International ed. in English) · 2019Article
Corrections and comments
- Erratum issued
Authors and funding
6 authors at 2 institutions in 1 country.
Funding
Abstract
Indoles are privileged heterocycles found in many biologically active pharmaceuticals and natural products. However, the selective functionalization of the benzenoid moiety in indoles in preference to the more reactive pyrrolic unit is a significant challenge. Herein we report that N-acyl directing groups enable the C7-selective C-H borylation of indoles using just BBr
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.