ArticleNature catalysis2019
Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization.
Article in Nature catalysis, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Deprotonation and Alkylation of Weakly Acidic C(spAngewandte Chemie (International ed. in English) · 2026Article
- Hydrogen Atom-Coupled Electron Transfer-Driven Anionic Polymerization under Aerobic Conditions.Research square · 2026Article
- Solvent-temperature coupled hydride transfer controls product selectivity in the HSiRChemical science · 2026Article
- Formation of cyclopentanes and cyclopropanes through alkylation of benzylic anions using ethers, thioethers and alcohols as substrates under Grubbs-Stoltz (EtChemical science · 2026Article
- Direct Carboboration of Aryl Alkenes with Stable Organoborons Through Ziegler-Type Addition.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Pressure-induced generation of heterogeneous electrocatalytic metal hydride surfaces for sustainable hydrogen transfer.Nature communications · 2024Article
- Stepwise on-demand functionalization of multihydrosilanes enabled by a hydrogen-atom-transfer photocatalyst based on eosin Y.Nature chemistry · 2023Article
- Uncanonical Semireduction of Quinolines and Isoquinolines via Regioselective HAT-Promoted Hydrosilylation.Journal of the American Chemical Society · 2023Article
- Synthesis and Characterization of Hypercoordinated Silicon Anions: Catching Intermediates of Lewis Base Catalysis.Angewandte Chemie (International ed. in English) · 2022Article
- Mechanistic Studies on the Hexadecafluorophthalocyanine-Iron-Catalyzed Wacker-Type Oxidation of Olefins to Ketones*.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Radical and Ionic Mechanisms in Rearrangements ofMolecules (Basel, Switzerland) · 2021Article
- Block-Localized Excitation for Excimer Complex and Diabatic Coupling.Journal of chemical theory and computation · 2021Article
- EtChemical science · 2020Article
- Mechanistic Aspects of Hydrosilane/PotassiumACS omega · 2020Review
- New reductive rearrangement ofChemical science · 2020Article
- Early Main Group Metal Catalysts for Imine Hydrosilylation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
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Authors and funding
14 authors.
Funding
Abstract
Because of the importance of hydrogen atom transfer (HAT) in biology and chemistry, there is increased interest in new strategies to perform HAT in a sustainable manner. Here, we describe a sustainable, net redox-neutral HAT process involving hydrosilanes and alkali metal Lewis base catalysts - eliminating the use of transition metal catalysts - and report an associated mechanism concerning Lewis base-catalysed, complexation-induced HAT (LBCI-HAT). The catalytic LBCI-HAT is capable of accessing both branch-specific hydrosilylation and polymerization of vinylarenes in a highly selective fashion, depending on the Lewis base catalyst used. In this process, earth abundant, alkali metal Lewis base catalyst plays a dual role. It first serves as a HAT initiator and subsequently functions as a silyl radical stabilizing group, which is critical to highly selective cross-radical coupling. EPR study identified a potassiated paramagnetic species and multistate density function theory revealed a high HAT character, yet multiconfigurational nature in the transition state of the reaction.
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