Evidence map›Paper›PMID 31460030›Full record

ArticleACS omega2019

Hexadecyl-Containing Organic Salts as Novel Organogelators for Ionic, Eutectic, and Molecular Liquids.

Cesar N Prieto Kullmer, Daniel Ta, Christian Y Chen, Christopher J Cieker, Onofrio Annunziata, Sergei V Dzyuba

Abstract read
In one paragraph

Article in ACS omega, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Cesar N Prieto KullmerDepartment of Chemistry and Biochemistry, Texas Christian University, Fort Worth, Texas 76129, United States.
Daniel TaDepartment of Chemistry and Biochemistry, Texas Christian University, Fort Worth, Texas 76129, United States.
Christian Y ChenDepartment of Chemistry and Biochemistry, Texas Christian University, Fort Worth, Texas 76129, United States.
Christopher J CiekerDepartment of Chemistry and Biochemistry, Texas Christian University, Fort Worth, Texas 76129, United States.
Onofrio AnnunziataDepartment of Chemistry and Biochemistry, Texas Christian University, Fort Worth, Texas 76129, United States.
Sergei V DzyubaDepartment of Chemistry and Biochemistry, Texas Christian University, Fort Worth, Texas 76129, United States.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The incorporation of a hexadecyl group on imidazolium, pyridinium, and pyrrolidinium scaffolds produces low-molecular-weight ionic organogelators that can gel several types of ionic liquids, deep eutectic solvents (DESs), and several molecular organic solvents. Minimum gelator concentrations fall in the 0.9-15.0% (w/v) range, with the lower end of the gelator concentrations observed in the gelation of DESs. On the basis of polarized optical microscopy, differential scanning calorimetry, and X-ray data, crystallization of these salts appear to produce high-surface-area crystals, which generate sufficiently stable three-dimensional networks that are capable of trapping the solvent molecules. Importantly, the nature of the fluid component of the gel appears to have a profound effect on the morphology of the crystallized organogelators. On the other hand, the organogelators appeared to modulate phase transitions of the liquids.

Identifiers

PMID31460030
PMCPMC6647963

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.