ArticleACS omega2019
Synthesis of Multifunctional Aryl(trifloxyalkenyl)iodonium Triflate Salts.
Article in ACS omega, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed.
- Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents.Chemical reviews · 2024Review
- A decade of lessons in the activation of ArILChemical science · 2024Review
- Synthesis and Structural Verification of an ArI(OTf)Angewandte Chemie (International ed. in English) · 2022Article
- Recent Advances in Transition-Metal-Free Late-Stage C-H and N-H Arylation of Heteroarenes Using Diaryliodonium Salts.Pharmaceuticals (Basel, Switzerland) · 2021Review
- Generation of Mixed Anhydrides via Oxidative Fragmentation of Tertiary Cyclopropanols with Phenyliodine(III) Dicarboxylates.Molecules (Basel, Switzerland) · 2020Article
- Vicinal difunctionalization of carbon-carbon double bond for the platform synthesis of trifluoroalkyl amines.Nature communications · 2020Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A convenient procedure for the synthesis of aryl(trifloxyalkenyl)iodonium triflate salts from commercially available (diacetoxyiodo)benzene, trimethylsilyl trifluoromethanesulfonate, and acetylenes under mild conditions was developed. The obtained multifunctional hypervalent vinyliodonium salts equipped with electrophilic and nucleophilic functions could serve as novel C2 synthons for organic transformations. The structure of the iodonium salts was identified by multidimensional NMR spectroscopy and X-ray crystallography.
Identifiers
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Registered trials
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