ArticleACS omega2019
Iron(III) Complexes for Highly Efficient and Sustainable Ketalization of Glycerol: A Combined Experimental and Theoretical Study.
Article in ACS omega, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Iron-Catalyzed Synthesis of 4‑oxo-1,3-dioxolanes (DOXs) Using Lactic Acid: From Homogeneous to Heterogeneous Behaviors.ACS sustainable chemistry & engineering · 2025Article
- Heteropoly Ionic Liquid Functionalized MOF-Fe: Synthesis, Characterization, and Catalytic Application in Selective Acetalization of Glycerol to Solketal as a Fuel Additive at Room Temperature, Solvent-Free Conditions.Precision chemistry · 2023Article
- Sustainable Ketalization of Glycerol with Ethyl Levulinate Catalyzed by the Iron(III)-Based Metal-Organic Framework MIL-88A.Molecules (Basel, Switzerland) · 2022Article
- Homogeneous Catalysis and Heterogeneous Recycling: A Simple Zn(II) Catalyst for Green Fatty Acid Esterification.ACS sustainable chemistry & engineering · 2021Article
- Catalytic Activity and Kinetic Modeling of Various Modules HZMS-5 and Treated MCM-41 Catalysts, for the Liquid-Phase Ketalization of Glycerol With Acetone.Frontiers in chemistry · 2019Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The growing production of biodiesel as a promising alternative and renewable fuel led as the main problem the dramatic increase of its by-product: glycerol. Different strategies for glycerol derivatization have been reported so far, some more efficient or sustainable than others. Herein, we report a very promising and eco-friendly transformation of glycerol in nontoxic solvents and chemicals (i.e., solketal, ketals), proposing three new families of Fe(III) compounds capable of catalysing glycerol acetalization with unpublished turn over frequencies (TOFs), and adhering most of the principles of green chemistry. The comparison between the activity of complexes of formula [FeCl
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Registered trials
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