ArticleACS omega2018
Study of the Degradation and Conservation of Historical Leather Book Covers with Macro Attenuated Total Reflection-Fourier Transform Infrared Spectroscopic Imaging.
Article in ACS omega, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed, 47 citations in OpenAlex.
- An integration of bacterial probiotic extract and green nanoparticles as a safe approach for conservation of historical manuscript against fungal deterioration: an applied study.Scientific reports · 2026Article
- Article
- Fungal Biodeterioration of a Historical Manuscript Dating Back to the 14th Century: An Insight into Various Fungal Strains and Their Enzymatic Activities.Life (Basel, Switzerland) · 2022Article
- Time-Resolved ATR-FTIR Spectroscopy and Macro ATR-FTIR Spectroscopic Imaging of Inorganic Treatments for Stone Conservation.Analytical chemistry · 2021Article
- Fatty Acids and Their Metal Salts: A Review of Their Infrared Spectra in Light of Their Presence in Cultural Heritage.Molecules (Basel, Switzerland) · 2021Review
- Recent developments in using the molecular decay dating method: a review.Annals of the New York Academy of Sciences · 2021Review
- Article
Corrections and comments
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Authors and funding
3 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The analytical study of historical collagen-based materials such as leather book covers is a complex task for conservation scientists. Historical leather presents a heterogeneous composition of both organic and inorganic materials that show an evident reactivity, particularly when exposed to specific environments. Its correct preservation in archival documents remains challenging as some aspects of its chemical composition, degradation, and effectiveness of conservation treatments are still not fully understood. Here, we describe a novel application of attenuated total reflection (ATR)-Fourier transform infrared spectroscopic imaging coupled with a macro ATR accessory to study historical leather book covers. This nondestructive and high spatial resolution approach has allowed the visualization of degradation phenomena affecting this fragile material, particularly the gelatinization of collagen and, for the first time, the detection of the formation of calcium stearate (metal carboxylates or soaps). In addition, the distribution of modified soybean oil used as a treatment to maintain properties such as elasticity and hydrophobicity of the leather was studied. The effect of anomalous dispersion on the strong IR bands obtained in the ATR mode and the resulting changes to the band positions are also discussed. This research addresses issues that are relevant to the conservation of archival materials of cultural heritage for future generations.
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Registered trials
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