ArticleACS omega2018
Magnetic Diversity in Heteroisocorroles: Aromatic Pathways in 10-Heteroatom-Substituted Isocorroles.
Article in ACS omega, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
4 citing papers in PubMed.
- Functionalization of β-Alkylcorrole Using Ag(I) Salts.Inorganic chemistry · 2026Article
- Doubly Stereogenic Sandwich Frameworks: Diastereomeric Metallobiscorroles.Inorganic chemistry · 2025Article
- Functional group introduction and aromatic unit variation in a set of π-conjugated macrocycles: revealing the central role of local and global aromaticity.Organic chemistry frontiers : an international journal of organic chemistry · 2021Article
- Fine-Tuning of Nonlinear Optical Contrasts of Hexaphyrin-Based Molecular Switches Using Inverse Design.Frontiers in chemistry · 2021Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A recent study on magnetically induced currents in 10-isocorrole derivatives indicated that both the free-base and metal-complexed forms of the unsubstituted macrocycle are homoaromatic. Furthermore, depending on the substituents at the 10-position, the aromatic character was found to swing between substantially homoaromatic to substantially antihomoaromatic. Heteroisocorroles, in which the saturated 10-position has been replaced by a heteroatom-containing group X, are predicted to exhibit even more dramatic variations in aromatic character, ranging from strongly aromatic (X = O, NH, PH, and S) to strongly antiaromatic (X = BH and CO). Interestingly, the experimentally studied X = SiMe
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Registered trials
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