Short Pulse Laser Synthesis of Transition-Metal Dichalcogenide Nanostructures under Ambient Conditions.

The study of inorganic nanometer-scale materials with hollow closed-cage structures, such as inorganic fullerene-like (IF) nanostructures and inorganic nanotubes (INTs), is a rapidly growing field. Numerous kinds of IF nanostructures and INTs were synthesized for a variety of applications, particularly for lubrication, functional coatings, and reinforcement of polymer matrices. To date, such nanostructures have been synthesized mostly by heating a transition metal or oxide thereof in the presence of precursor gases, which are however toxic and hazardous. In this context, one frontier of research in this field is the development of new avenues for the green synthesis of IF structures and INTs, directly from the bulk of layered compounds. In the present work, we demonstrate a simple room-temperature and environmentally friendly approach for the synthesis of IF nanostructures and INTs via ultrashort-pulse laser ablation of a mixture of transition-metal dichalcogenides in bulk form mixed with Pb/PbO, in ambient air. The method can be considered as a synergy of photothermally and photochemically induced chemical transformations. The ultrafast-laser-induced excitation of the material, complemented with the formation of extended hot annealing regions in the presence of the metal catalyst, facilitates the formation of different nanostructures. Being fast, easy, and material-independent, our method offers new opportunities for the synthesis of IF nanostructures and INTs from different bulk metal chalcogenide compounds. On the basis of the capabilities of laser technology as well, this method could advantageously be further developed into a versatile tool for the simultaneous growth and patterning of such nanostructures in preselected positions for a variety of applications.