ArticleACS omega2017
Selective Synthesis of (Benzyl)biphenyls by Successive Suzuki-Miyaura Coupling of Phenylboronic Acids with 4-Bromobenzyl Acetate under Air Atmosphere.
Article in ACS omega, 2017. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Nickel-catalyzed arylative substitution of homoallylic alcohols.Chemical science · 2022Article
- Synthesis of Triarylmethanes via Palladium-Catalyzed Suzuki-Miyaura Reactions of Diarylmethyl Esters.Organometallics · 2021Article
- Nickel(II) Nanoparticles Immobilized on EDTA-Modified FeACS omega · 2020Article
- Substrate switchable Suzuki-Miyaura coupling for benzyl esterRSC advances · 2018Article
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Authors and funding
2 authors.
Funding
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Abstract
An efficient Pd-catalyzed cross-coupling reaction of phenylboronic acids and benzyl carbonates was developed, producing diarylmethanes. Benzyl acetates could also be used as coupling partners instead of benzyl carbonates, affording diarylmethanes in comparable yields. This reaction can be conducted under air atmosphere without any care for moisture and oxygen. The ester function showed an intermediate reactivity between chloro and bromo groups. This property facilitated the selective synthesis of diverse (benzyl)biphenyls by successive Suzuki-Miyaura coupling reactions using bromo- and chloro-substituted benzyl esters with two types of boronic acids.
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Registered trials
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