ArticleNature communications2019
Atomistic structures and dynamics of prenucleation clusters in MOF-2 and MOF-5 syntheses.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- In Situ Insights into Enhanced Cooperative Ligand Exchange Kinetics via Solvent-Induced Restacking in a 2D Metal-Organic Framework.Journal of the American Chemical Society · 2026Article
- Computational Modeling of Reticular Materials: The Past, the Present, and the Future.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Prognosis of simplified metal and organic sites resembling a quasi-MOF structure for hydrogen storage: investigation and insight.RSC advances · 2025Article
- Recent Advances in Transition Metal-Based Metal-Organic Frameworks for Hydrogen Production.Small science · 2025Review
- Validation and Mechanistic Studies of the Headspace Effect in MOF Synthesis.Angewandte Chemie (International ed. in English) · 2025Article
- Unveiling the Dynamic Pathways of Metal-Organic Framework Crystallization and Nanoparticle Incorporation for Li-S Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Branched Polymeric Prenucleation Assemblies Initiate Calcium Phosphate Precipitation.Journal of the American Chemical Society · 2024Article
- Synthetic and analytical considerations for the preparation of amorphous metal-organic frameworks.Chemical science · 2024Review
- Disproportionation chemistry in KScience advances · 2024Article
- Multi-step nucleation pathway of C-S-H during cement hydration from atomistic simulations.Nature communications · 2023Article
- Time-resolved imaging and analysis of the electron beam-induced formation of an open-cage metallo-azafullerene.Nature chemistry · 2023Article
- Research Progress on Metal-Organic Frameworks by Advanced Transmission Electron Microscopy.Nanomaterials (Basel, Switzerland) · 2023Review
- Article
- Ionization and electron excitation of CProceedings of the National Academy of Sciences of the United States of America · 2022Article
- Atomic-number (Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- FromChemistry of materials : a publication of the American Chemical Society · 2022Article
- Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly.Beilstein journal of nanotechnology · 2022Review
- MOFs in the time domain.Nature reviews. Chemistry · 2022Review
- Metal atom-guided conformational analysis of single polynuclear coordination molecules.Science advances · 2021Article
- Progress in Molecular Nanoarchitectonics and Materials Nanoarchitectonics.Molecules (Basel, Switzerland) · 2021Review
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Chemical reactions in solution almost always take place via a series of minute intermediates that are often in rapid equilibrium with each other, and hence hardly characterizable at the level of atomistic molecular structures. We found that single-molecule atomic-resolution real-time electron microscopic (SMART-EM) video imaging provides a unique methodology for capturing and analyzing the minute reaction intermediates, as illustrated here for single prenucleation clusters (PNCs) in the reaction mixture of metal-organic frameworks (MOFs). Specifically, we found two different types of PNCs are involved in the formation of MOF-2 and MOF-5 from a mixture of zinc nitrate and benzene dicarboxylates at 95 °C and 120 °C, respectively. SMART-EM identified a small amount of 1-nm-sized cube and cube-like PNCs in the MOF-5 synthesis, but not in the MOF-2 synthesis. In the latter, we instead found only linear and square PNCs, suggesting that the MOF-2/-5 bifurcation takes place at the PNC stage.
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Registered trials
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