ArticleNature chemistry2019
Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(V)-dinitrogen complex.
Article in Nature chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed, 69 citations in OpenAlex.
- Catalytic and stoichiometric stepwise conversion of side-on bound dinitrogen to ammonia mediated by a uranium complex.Nature chemistry · 2025Article
- Polyol-Intermediated Facile Synthesis of BSmall (Weinheim an der Bergstrasse, Germany) · 2025Article
- Resonant inelastic X-ray scattering tools to count 5 f electrons of actinides and probe bond covalency.Nature communications · 2025Article
- Review
- Coordination-Induced Magnetism Strategy for Highly Selective and Efficient Uranium Separation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Multiconfigurational actinide nitrides assisted by double Möbius aromaticity.Chemical science · 2024Article
- Progress in Nonaqueous Molecular Uranium Chemistry: Where to Next?Inorganic chemistry · 2024Article
- Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides.Chemical science · 2024Article
- Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs.Journal of the American Chemical Society · 2024Article
- Article
- Dinitrogen cleavage by a dinuclear uranium(iii) complex.Chemical science · 2023Article
- Steering competitive NChemical science · 2023Article
- Reduction of KJournal of the American Chemical Society · 2023Article
- Progress in the chemistry of molecular actinide-nitride compounds.Chemical science · 2023Review
- Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex.National science review · 2023Article
- Cation assisted binding and cleavage of dinitrogen by uranium complexes.Chemical science · 2022Article
- Nitrogen activation and cleavage by a multimetallic uranium complex.Chemical science · 2022Article
- Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV).Organometallics · 2022Article
- Carbene Complexes of Neptunium.Journal of the American Chemical Society · 2022Article
- NFrontiers in chemistry · 2022Article
Corrections and comments
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Authors and funding
12 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A fundamental bonding model in coordination and organometallic chemistry is the synergic, donor-acceptor interaction between a metal and a neutral π-acceptor ligand, in which the ligand σ donates to the metal, which π back-bonds to the ligand. This interaction typically involves a metal with an electron-rich, mid-, low- or even negative oxidation state and a ligand with a π* orbital. Here, we report that treatment of a uranium-carbene complex with an organoazide produces a uranium(V)-bis(imido)-dinitrogen complex, stabilized by a lithium counterion. This complex, which was isolated in a crystalline form, involves an electron-poor, high-oxidation-state uranium(V) 5f
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