Evidence map›Paper›PMID 31409937›Full record

ArticleJournal of solution chemistry2019

Binary Mixtures of Ionic Liquids in Aqueous Solution: Towards an Understanding of their Salting-In/Salting-Out Phenomena.

Catarina M S S Neves, Teresa B V Dinis, Pedro J Carvalho, Bernd Schröder, Luís M N B F Santos, Mara G Freire, João A P Coutinho

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of solution chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
  2. Computational NMR Spectroscopy of Ionic Liquids: [CMolecules (Basel, Switzerland) · 2020
    Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Catarina M S S NevesCICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.
Teresa B V DinisCICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.
Pedro J CarvalhoCICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.
Bernd SchröderCICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.
Luís M N B F SantosCIQUP-Centro de Investigação em Química da Universidade do Porto, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto, Portugal.
Mara G FreireCICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.
João A P CoutinhoCICECO - Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.

Funding

European Research Council 337753
6 · The paper itself

Abstract

The order of the salting-in or salting-out inducing ability of ions on the aqueous solubility of macromolecules in aqueous solutions is known as the Hofmeister series. Taking into account that ionic liquids (ILs) are constituted by ions, they can exert similar effects on the solubility of other ILs in aqueous media. In order to expand the knowledge on the salting-in/-out ability of ILs, experimental studies on the solubility of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonylimide) in water in presence of other IL/salts were conducted at 298.15 K at atmospheric pressure. Both the impact of the anion and cation of the IL were evaluated with the following ILs/salts: 1-butyl-3-methylimidazolium chloride, 1-butyl-3-methylimidazolium hydrogensulfate, cholinium bis(trifluoromethylsulfonyl)imide, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide and lithium bis(trifluoromethylsulfonyl)imide, in a wide composition range. As happens with common salts, both salting-in and salting-out effects exerted by ILs were observed, with a higher impact exerted by the IL anion on the salting-out phenomenon. These data allow to better understand the ILs impact when designing liquid-liquid separation processes.

Indexed as

Hofmeister seriesIonic LiquidsSalting-in effectSalting-out effectSolubilityWater

Identifiers

PMID31409937
PMCPMC6692162

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.