ArticleNature chemistry2019
Ultra-fast intramolecular singlet fission to persistent multiexcitons by molecular design.
Article in Nature chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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Who cites it
31 citing papers in PubMed.
- Singlet fission mediates carotenoid-to-bacteriochlorophyll energy transfer in purple photosynthetic bacteria.Nature chemistry · 2026Article
- An Energy-Gradient Strategy for Triplet-Pair Separation in Singlet-Fission Oligomers.Journal of the American Chemical Society · 2026Article
- Dual role of a conjugated bridge in intramolecular singlet fission: light-harvesting antenna and energy funnel.Chemical science · 2026Article
- Electron transfer from singlet fission dimers: possibilities and limitations.Chemical science · 2026Article
- Excimer-mediated multiexciton generation in covalently linked cross foldamers of thiophene-fused perylene bisimides.Chemical science · 2026Article
- Controlling triplet-pair formation in acene-bridged trimers through locally excited-charge-transfer state mixing.Chemical science · 2026Article
- Singlet Fission Luminescent Solar Concentrators.Nano letters · 2025Article
- Tuning the Inter-Chromophore Electronic Coupling in Perylene Diimide Dimers with Rigid Covalent Linkers.Molecules (Basel, Switzerland) · 2025Article
- Intramolecular Singlet Fission in Individual Graphene Nanoribbons─Competition with a Charge Transfer.Journal of the American Chemical Society · 2025Article
- The Interplay of Strongly and Weakly Exchange-Coupled Triplet Pairs in Intramolecular Singlet Fission.Journal of the American Chemical Society · 2024Article
- Long-Lived Triplets from Singlet Fission in Pentacene-Decorated Helical Supramolecular Polymers.Journal of the American Chemical Society · 2024Article
- Revealing the Singlet Fission Mechanism for a Silane-Bridged Thienotetracene Dimer.The journal of physical chemistry. A · 2024Article
- Enhancing NIR-to-visible upconversion in a rigidly coupled tetracene dimer: approaching statistical limits for triplet-triplet annihilation using intramolecular multiexciton states.Chemical science · 2024Article
- Multiexciton quintet state populations in a rigid pyrene-bridged parallel tetracene dimer.Chemical science · 2023Article
- Promoting multiexciton interactions in singlet fission and triplet fusion upconversion dendrimers.Nature communications · 2023Article
- Twisted Carotenoids Do Not Support Efficient Intramolecular Singlet Fission in the Orange Carotenoid Protein.The journal of physical chemistry letters · 2023Article
- Photogeneration of Spin Quintet Triplet-Triplet Excitations in DNA-Assembled Pentacene Stacks.Journal of the American Chemical Society · 2023Article
- Quantum interference effects elucidate triplet-pair formation dynamics in intramolecular singlet-fission molecules.Nature chemistry · 2023Article
- Soluble Diphenylhexatriene Dimers for Intramolecular Singlet Fission with High Triplet Energy.Journal of the American Chemical Society · 2023Article
- Singlet fission dynamics modulated by molecular configuration in covalently linked pyrene dimers, Anti- and Syn-1,2-di(pyrenyl)benzene.Communications chemistry · 2023Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Singlet fission-that is, the generation of two triplets from a lone singlet state-has recently resurfaced as a promising process for the generation of multiexcitons in organic systems. Although advances in this area have led to the discovery of modular classes of chromophores, controlling the fate of the multiexciton states has been a major challenge; for example, promoting fast multiexciton generation while maintaining long triplet lifetimes. Unravelling the dynamical evolution of the spin- and energy conversion processes from the transition of singlet excitons to correlated triplet pairs and individual triplet excitons is necessary to design materials that are optimized for translational technologies. Here, we engineer molecules featuring a discrete energy gradient that promotes the migration of strongly coupled triplet pairs to a spatially separated, weakly coupled state that readily dissociates into free triplets. This 'energy cleft' concept allows us to combine the amplification and migration processes within a single molecule, with rapid dissociation of tightly bound triplet pairs into individual triplets that exhibit lifetimes of ~20 µs.
Identifiers
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Registered trials
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