Evidence map›Paper›PMID 31399565›Full record

ArticleNature communications2019

Tracking multiple components of a nuclear wavepacket in photoexcited Cu(I)-phenanthroline complex using ultrafast X-ray spectroscopy.

Tetsuo Katayama, Thomas Northey, Wojciech Gawelda, Christopher J Milne, György Vankó, Frederico A Lima, Rok Bohinc, Zoltán Németh, Shunsuke Nozawa, Tokushi Sato and 8 more

Abstract read
In one paragraph

Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.

0numbers the graph read from it
0cells of the map it votes in
25citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

25 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

18 authors.

Tetsuo KatayamaJapan Synchrotron Radiation Research Institute, Kouto 1-1-1, Sayo, Hyogo, 679-5198, Japan. tetsuo@spring8.or.jp.ORCID http://orcid.org/0000-0002-2681-8316
Thomas NortheyChemistry-School of Natural and Environmental Sciences, Newcastle University, Newcastle Upon-Tyne, NE1 7RU, UK.
Wojciech GaweldaEuropean XFEL, Holzkoppel 4, 22869, Schenefeld, Germany.ORCID http://orcid.org/0000-0001-7824-9197
Christopher J MilneSwissFEL, Paul Scherrer Institut, 5232, Villigen-PSI, Switzerland.ORCID http://orcid.org/0000-0003-4714-9139
György VankóWigner Research Centre for Physics, Hungarian Academy of Sciences, 1525, Budapest, Hungary.ORCID http://orcid.org/0000-0002-3095-6551
Frederico A LimaEuropean XFEL, Holzkoppel 4, 22869, Schenefeld, Germany.
Rok BohincSwissFEL, Paul Scherrer Institut, 5232, Villigen-PSI, Switzerland.ORCID http://orcid.org/0000-0002-2971-6358
Zoltán NémethWigner Research Centre for Physics, Hungarian Academy of Sciences, 1525, Budapest, Hungary.
Shunsuke NozawaInstitute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki, 305-0801, Japan.
Tokushi SatoEuropean XFEL, Holzkoppel 4, 22869, Schenefeld, Germany.
Dmitry KhakhulinEuropean XFEL, Holzkoppel 4, 22869, Schenefeld, Germany.
Jakub SzlachetkoInstitute of Nuclear Physics, Polish Academy of Sciences, 31-342, Kraków, Poland.ORCID http://orcid.org/0000-0002-7526-3097
Tadashi TogashiJapan Synchrotron Radiation Research Institute, Kouto 1-1-1, Sayo, Hyogo, 679-5198, Japan.
Shigeki OwadaJapan Synchrotron Radiation Research Institute, Kouto 1-1-1, Sayo, Hyogo, 679-5198, Japan.
Shin-Ichi AdachiInstitute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba, Ibaraki, 305-0801, Japan.
Christian BresslerEuropean XFEL, Holzkoppel 4, 22869, Schenefeld, Germany.
Makina YabashiRIKEN SPring-8 Center, 1-1-1 Kouto, Sayo, Hyogo, 679-5148, Japan.ORCID http://orcid.org/0000-0002-2472-1684
Thomas J PenfoldChemistry-School of Natural and Environmental Sciences, Newcastle University, Newcastle Upon-Tyne, NE1 7RU, UK. tom.penfold@ncl.ac.uk.

Funding

Leverhulme Trust RPG-2016-103MEXT | Japan Society for the Promotion of Science (JSPS) JP17H06141MEXT | Japan Society for the Promotion of Science (JSPS) JP19H04407MEXT | Japan Society for the Promotion of Science (JSPS) JP19H05782RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/R021503/1
6 · The paper itself

Abstract

Disentangling the strong interplay between electronic and nuclear degrees of freedom is essential to achieve a full understanding of excited state processes during ultrafast nonadiabatic chemical reactions. However, the complexity of multi-dimensional potential energy surfaces means that this remains challenging. The energy flow during vibrational and electronic relaxation processes can be explored with structural sensitivity by probing a nuclear wavepacket using femtosecond time-resolved X-ray Absorption Near Edge Structure (TR-XANES). However, it remains unknown to what level of detail vibrational motions are observable in this X-ray technique. Herein we track the wavepacket dynamics of a prototypical [Cu(2,9-dimethyl-1,10-phenanthroline)

Identifiers

PMID31399565
PMCPMC6689108

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.