ArticleOrganic process research & development2019
Solubility of Iridium and Ruthenium Organometallic Photoredox Catalysts.
Article in Organic process research & development, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Polyelectrolyte Copolymer Nanoreactors: From Colloidal Assembly to Photoredox Activity in Water.ACS applied materials & interfaces · 2026Article
- Base Metal Photocatalysts: A Bright Future in Photoredox Catalysis?Organometallics · 2026Article
- Machine Learning-Driven Optimization of Continuous-Flow Photoredox Amine Synthesis.Organic process research & development · 2025Article
- Exploiting a New Strategy to Prepare Water-Soluble Heteroleptic Iridium(III) Complexes to Control Electrochemiluminescence Reaction Pathways in Aqueous Solution.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Synthesis and Characterization of Iridium(III) Complexes with Substituted Phenylimidazo(4,5-Molecules (Basel, Switzerland) · 2023Article
- Photocatalytic Regeneration of a Nicotinamide Adenine Nucleotide Mimic with Water-Soluble Iridium(III) Complexes.Inorganic chemistry · 2023Article
- Visible-Light Photoredox Catalysis in Water.The Journal of organic chemistry · 2023Review
- Energy transfer (EnT) photocatalysis enabled by gold-N-heterocyclic carbene (NHC) complexes.Chemical science · 2022Article
- Water-Soluble Tris(cyclometalated) Iridium(III) Complexes for Aqueous Electron and Energy Transfer Photochemistry.Accounts of chemical research · 2022Review
- Flavin Metallaphotoredox Catalysis: Synergistic Synthesis in Water.ACS catalysis · 2022Article
- Water-Soluble Iridium Photoredox Catalyst for the Trifluoromethylation of Biomolecule Substrates in Phosphate Buffered Saline Solvent.Organic letters · 2021Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Despite the exponential growth of the field of photocatalysis, for reasons that are not entirely clear, these precious photocatalysts are often used in the literature at loadings that exceed their maximum solubility. On an industrial scale, the quantity of any precious metal catalyst can be a substantial financial burden or a sourcing issue, not to mention concerns as to the ecological and earth abundance of these catalysts. We believe that inattention to solubility has made these reactions appear less efficient than they actually are, because much of the photocatalyst remains undissolved. Therefore, the maximum solubilities of iridium and ruthenium centered photocatalysts have been systematically identified in industrially relevant solvents. Further, a literature photocatalytic reaction which our results suggested was beyond the maximum solubility has been revisited, with interesting results.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.