ArticleChemical science2019
Interplay between spin-crossover and luminescence in a multifunctional single crystal iron(ii) complex: towards a new generation of molecular sensors.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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14 citing papers in PubMed.
- TChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Synergetic Spin-Crossover and Luminescence in a Fe(II) Complex with Aggregation-Induced Emission and Twisted Intramolecular Charge Transfer.Precision chemistry · 2025Article
- Article
- Bidirectional photomagnetism, exciplex fluorescence and dielectric anomalies in a spin crossover Hofmann-type coordination polymer.Chemical science · 2024Article
- Optical Phenomena in Molecule-Based Magnetic Materials.Chemical reviews · 2024Review
- Defying the inverse energy gap law: a vacuum-evaporable Fe(ii) low-spin complex with a long-lived LIESST state.Chemical science · 2023Article
- The Influence of the Substrate on the Functionality of Spin Crossover Molecular Materials.Molecules (Basel, Switzerland) · 2023Review
- Electro-Elastic Modeling of Thermal Spin Transition in Diluted Spin-Crossover Single Crystals.International journal of molecular sciences · 2022Article
- High-Temperature Spin Crossover in Iron(II) Complexes with 2,6-Bis(1Molecules (Basel, Switzerland) · 2022Article
- Manganese(I) Complex with Monodentate Arylisocyanide Ligands Shows Photodissociation Instead of Luminescence.Inorganic chemistry · 2022Article
- Homochiral MnInorganic chemistry · 2022Article
- Bistable Hofmann-Type FeInorganic chemistry · 2021Article
- Holmium(iii) molecular nanomagnets for optical thermometry exploring the luminescence re-absorption effect.Chemical science · 2020Article
- Reversible guest-induced gate-opening with multiplex spin crossover responses in two-dimensional Hofmann clathrates.Chemical science · 2020Article
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11 authors.
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Abstract
We present a new example of a mononuclear iron(ii) complex exhibiting a correlated spin-crossover (SCO) transition and strong fluorescence, whose coordination sphere is saturated, for the first time, by six phosphorescent ligands. The interplay between SCO and light emission properties in the thermal region of the spin transition was investigated by means of magnetic, fluorescence, optical absorption and optical microscopy measurements on a single crystal. Overall, the results show an excellent correlation between fluorescence and magnetic data of the present gradual transition, indicating an extreme sensitivity of the optical activity of the ligand to the spin state of the active iron(ii) ions. These results open the way for conceiving new prototypes of pressure and temperature sensors based on this synergy between SCO and luminescence properties. In particular, the fact that cooperative SCO material is not a prerequisite for obtaining such synergetic effects, is useful for the design of thin films or nanoparticles, in which the cooperativity is reduced, for appropriate implementation in nanosized devices to enhance the sensing properties at the nanoscale.
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