ArticleChemical science2019
Living supramolecular polymerization based on reversible deactivation of a monomer by using a 'dummy' monomer.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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15 citing papers in PubMed.
- Supramolecular Polymerization and Morphological Transformation of Dynamic Helical Poly(Phenylacetylene)s via Chain-End Host-Guest Interactions.Angewandte Chemie (International ed. in English) · 2026Article
- Kinetically controlled self-assembly of Zn-porphyrin nanostructuresRSC advances · 2025Article
- Vortex-Flow-Directed Chiral Macroscopic Ordering of Platelet Nanostructures Formed via the Supramolecular Assembly of Platinum Complexes with Bis(phenylisoxazolyl)benzene.Journal of the American Chemical Society · 2025Article
- Secondary nucleation as a strategy towards hierarchically organized mesoscale topologies in supramolecular polymerization.Nature chemistry · 2025Review
- Mechanosensitive non-equilibrium supramolecular polymerization in closed chemical systems.Nature communications · 2023Article
- Individually separated supramolecular polymer chains toward solution-processable supramolecular polymeric materials.Chemical science · 2023Article
- Transient chirality inversion during racemization of a helical cobalt(III) complex.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Hierarchical self-assembly of aromatic peptide conjugates into supramolecular polymers: it takes two to tango.Chemical science · 2022Review
- Consequences of Amide Connectivity in the Supramolecular Polymerization of Porphyrins: Spectroscopic Observations Rationalized by Theoretical Modelling.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Living supramolecular polymerization of fluorinated cyclohexanes.Nature communications · 2021Article
- Oriented arrangement of simple monomers enabled by confinement: towards living supramolecular polymerization.Nature communications · 2021Article
- Controlled synthesis of organic two-dimensional nanostructuresChemical science · 2020Article
- Supramolecular double-stranded Archimedean spirals and concentric toroids.Nature communications · 2020Article
- Consequences of hidden kinetic pathways on supramolecular polymerization.Chemical science · 2020Article
- Quantification of energy of activation to supramolecular nanofibre formation reveals enthalpic and entropic effects and morphological consequence.Chemical science · 2019Article
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Authors and funding
4 authors.
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Abstract
Although living supramolecular polymerization (LSP) has recently been realized, the scope of the monomer structures applicable to the existing methods is still limited. For instance, a monomer that spontaneously nucleates itself cannot be processed in a manner consistent with LSP. Herein, we report a new method for such a "reactive" monomer. We use a 'dummy' monomer which has a similar structure to the reactive monomer but is incapable of one-dimensional supramolecular polymerization. We show that in the presence of the dummy monomer, the reactive monomer is kinetically trapped in the dormant state. In this way, spontaneous nucleation of the reactive monomer is retarded; yet, addition of seeds of a supramolecular polymer can initiate the supramolecular polymerization in a chain growth manner. As a result, we obtain the supramolecular polymer of the reactive monomer with a controlled length, which is otherwise thermodynamically inaccessible. We believe that this concept will expand the scope of LSP for the synthesis of other functional supramolecular polymers, and thus lead to a variety of applications.
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