Evidence map›Paper›PMID 31390474›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Enantioselective Radical Addition/Cross-Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents.

Matteo Chierchia, Peilin Xu, Gabriel J Lovinger, James P Morken

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.

0numbers the graph read from it
0cells of the map it votes in
32citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

32 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Matteo ChierchiaDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467, USA.
Peilin XuDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467, USA.
Gabriel J LovingerDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467, USA.
James P MorkenDepartment of Chemistry, Boston College, 2609 Beacon Street, Chestnut Hill, MA, 02467, USA.ORCID 0000-0002-9123-9791

Funding

New Strategies in Catalytic Organic Synthesis with Organoboron ReagentsR35GM127140 · NIGMS · BOSTON COLLEGE · PI JAMES Patrick MORKEN · 2018 to 2026
$5.1M
NIGMS NIH HHS R35 GM127140
6 · The paper itself

Abstract

A hybrid transition-metal/radical process is described that results in the addition of organozinc reagents and alkyl halides across alkenyl boron reagents in an enantioselective catalytic fashion. The reaction can be accomplished both intermolecularly and intramolecularly, providing useful product yields and high enantioselectivities in both manifolds.

Indexed as

AlcoholsBoron CompoundsFree RadicalsHydrocarbons, IodinatedMolecular StructureOrganometallic CompoundsStereoisomerismZincAlcoholsBoron CompoundsFree RadicalsHydrocarbons, IodinatedOrganometallic CompoundsZincboroncatalysiscross-couplingnickelradical reactions

Identifiers

PMID31390474
PMCPMC6764867

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.