ArticleNature chemistry2019
Photosensitized oxidative addition to gold(I) enables alkynylative cyclization of o-alkylnylphenols with iodoalkynes.
Article in Nature chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
23 citing papers in PubMed.
- Photosensitizing Au(I) Catalysis With Coumarins.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- β-Carbon functionalization of amines via α-amino Cu-carbenes.Science advances · 2026Article
- Bidentate mixed-ligand strategy in dinuclear gold photoredox catalysis.Nature communications · 2025Article
- Bidentate N-ligand-assisted gold redox catalysis with hydrogen peroxide.Nature chemistry · 2025Article
- Alkynyl Radicals, Myths and Realities.JACS Au · 2025Review
- Photosensitized Reductive Elimination of Gold(III) to Enable Esterification of Aryl Iodides with Carboxylic Acids.JACS Au · 2024Article
- Base-assisted transmetalation enables gold-catalyzed oxidative Sonogashira coupling reaction.iScience · 2024Article
- A Hemilabile NHC-Gold Complex and its Application to the Redox Neutral 1,2-Oxyarylation of Feedstock Alkenes.Angewandte Chemie (International ed. in English) · 2023Article
- Combined Catalysis: A Powerful Strategy for Engineering Multifunctional Sustainable Lignin-Based Materials.ACS nano · 2023Review
- On the Role of Noncovalent Ligand-Substrate Interactions in Au(I) Catalysis: An Experimental and Computational Study of Protodeauration.ACS catalysis · 2022Article
- Kinetics of a Ni/Ir-Photocatalyzed Coupling of ArBr with RBr: Intermediacy of ArNiJournal of the American Chemical Society · 2022Article
- Photoinduced inverse Sonogashira coupling reaction.Chemical science · 2022Article
- Mechanistic insights into photochemical nickel-catalyzed cross-couplings enabled by energy transfer.Nature communications · 2022Article
- Reactant-induced photoactivation of in situ generated organogold intermediates leading to alkynylated indoles via CspNature communications · 2022Article
- Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones.The Journal of organic chemistry · 2022Article
- Organometallic catalysis under visible light activation: benefits and preliminary rationales.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2022Article
- Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.Chemical reviews · 2022Review
- A Systematic Study of the Effects of Complex Structure on Aryl Iodide Oxidative Addition at Bipyridyl-Ligated Gold(I) Centers.Angewandte Chemie (International ed. in English) · 2021Article
- Au-Ag Bimetallic Catalysis: 3-Alkynyl Benzofurans from Phenols via Tandem C-H Alkynylation/Oxy-Alkynylation.Angewandte Chemie (International ed. in English) · 2021Article
- Oxidative additions of alkynyl/vinyl iodides to gold and gold-catalyzed vinylation reactions triggered by the MeDalphos ligand.Chemical science · 2021Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The well-established oxidative addition-reductive elimination pathway is the most followed one in transition metal-catalysed cross-coupling reactions. While readily occurring with a series of transition metals, gold(I) complexes have shown some reluctance to undergo oxidative addition unless special sets of ligands on gold(I), reagents or reaction conditions are used. Here we show that under visible-light irradiation, an iridium photocatalyst triggers-via triplet sensitization-the oxidative addition of an alkynyl iodide onto a vinylgold(I) intermediate to deliver C(sp)
Identifiers
31383980What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.