Evidence map›Paper›PMID 31379048›Full record

ReviewAngewandte Chemie (International ed. in English)2019

Individual-Molecule Perspective Analysis of Chemical Reaction Networks: The Case of a Light-Driven Supramolecular Pump.

Andrea Sabatino, Emanuele Penocchio, Giulio Ragazzon, Alberto Credi, Diego Frezzato

Abstract readReview
In one paragraph

Review in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Light-Driven Supramolecular Pumping by Changing Shape Complementarity.Journal of the American Chemical Society · 2026
    Article
  2. Article
  3. Controlling Swing Rates in Macrocyclic Molecular Mortise Hinges.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023
    Article
  4. Review
  5. Photochemical Energy Conversion with Artificial Molecular Machines.Energy & fuels : an American Chemical Society journal · 2021
    Review
  6. Artificial Supramolecular Pumps Powered by Light.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021
    Article
  7. Second-Generation Light-Fueled Supramolecular Pump.Journal of the American Chemical Society · 2021
    Article
  8. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Andrea SabatinoDipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131, Padova, Italy.
Emanuele PenocchioComplex Systems and Statistical Mechanics, Physics and Materials Science Unit, University of Luxembourg, 162 A, avenue de la Faïencerie, 1511, Luxembourg, Luxembourg.
Giulio RagazzonDepartment of Chemical and Pharmaceutical Sciences, Università degli Studi di Trieste, via Giorgieri 1, 34127, Trieste, Italy.ORCID http://orcid.org/0000-0002-7183-2985
Alberto CrediCenter for Light Activated Nanostructures (CLAN), Dipartimento di Scienze e Tecnologie Agro-alimentari, Università di Bologna, and Istituto ISOF, Consiglio Nazionale delle Ricerche, Via Gobetti 101, 40129, Bologna, Italy.ORCID http://orcid.org/0000-0003-2546-9801
Diego FrezzatoDipartimento di Scienze Chimiche, Università degli Studi di Padova, Via Marzolo 1, 35131, Padova, Italy.ORCID http://orcid.org/0000-0002-9107-2899

Funding

H2020 European Research Council 681456H2020 European Research Council 692981
6 · The paper itself

Abstract

The first study in which stochastic simulations of a two-component molecular machine are performed in the mass-action regime is presented. This system is an autonomous molecular pump consisting of a photoactive axle that creates a directed flow of rings through it by exploiting light energy away from equilibrium. The investigation demonstrates that the pump can operate in two regimes, both experimentally accessible, in which light-driven steps can be rate-determining or not. The number of photons exploited by an individual molecular pump, as well as the precision of cycling and the overall efficiency, critically rely on the operating regime of the machine. This approach provides useful information not only to guide the chemical design of a self-assembling molecular device with desired features, but also to elucidate the effect of the environment on its performance, thus facilitating its experimental investigation.

Indexed as

molecular machinesnonequilibrium processesreaction networksself-assemblysystems chemistry

Identifiers

PMID31379048
PMCPMC6899705

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.