Evidence map›Paper›PMID 31367319›Full record

ArticleChemical science2019

Solvent-assisted coordination driven assembly of a supramolecular architecture featuring two types of connectivity from discrete nanocages.

Zheng Niu, Lei Wang, Sheng Fang, Pui Ching Lan, Briana Aguila, Jason Perman, Jian-Gong Ma, Peng Cheng, Xiaopeng Li, Shengqian Ma

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Zheng NiuDepartment of Chemistry , University of South Florida , 4202 E. Fowler Avenue , Tampa , Florida 33620 , USA . Email: sqma@usf.edu.
Lei WangDepartment of Chemistry , University of South Florida , 4202 E. Fowler Avenue , Tampa , Florida 33620 , USA . Email: sqma@usf.edu.
Sheng FangDepartment of Chemistry , Institution Key Laboratory of Advanced Energy Materials Chemistry (MOE) , Collaborative Innovation Center of Chemical Science and Engineering , Nankai University , Tianjin 300071 , P. R. China.
Pui Ching LanDepartment of Chemistry , University of South Florida , 4202 E. Fowler Avenue , Tampa , Florida 33620 , USA . Email: sqma@usf.edu.
Briana AguilaDepartment of Chemistry , University of South Florida , 4202 E. Fowler Avenue , Tampa , Florida 33620 , USA . Email: sqma@usf.edu.ORCID 0000-0001-5997-3737
Jason PermanDepartment of Chemistry , University of South Florida , 4202 E. Fowler Avenue , Tampa , Florida 33620 , USA . Email: sqma@usf.edu.ORCID 0000-0003-4894-3561
Jian-Gong MaDepartment of Chemistry , Institution Key Laboratory of Advanced Energy Materials Chemistry (MOE) , Collaborative Innovation Center of Chemical Science and Engineering , Nankai University , Tianjin 300071 , P. R. China.ORCID 0000-0001-7407-5521
Peng ChengDepartment of Chemistry , Institution Key Laboratory of Advanced Energy Materials Chemistry (MOE) , Collaborative Innovation Center of Chemical Science and Engineering , Nankai University , Tianjin 300071 , P. R. China.ORCID 0000-0003-0396-1846
Xiaopeng LiDepartment of Chemistry , University of South Florida , 4202 E. Fowler Avenue , Tampa , Florida 33620 , USA . Email: sqma@usf.edu.ORCID 0000-0001-9655-9551
Shengqian MaDepartment of Chemistry , University of South Florida , 4202 E. Fowler Avenue , Tampa , Florida 33620 , USA . Email: sqma@usf.edu.ORCID 0000-0002-1897-7069

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The rapid development of supramolecular chemistry provides a powerful bottom-up approach to construct various well-defined nano-architectures with increasing complexity and functionality. Compared to that of small and simple nanometric objects, the self-assembly of larger and more complex nanometric objects, such as nanocages, remains a significant challenge. Herein, we used a discrete nanocage as the monomer to successfully construct a novel three-dimensional (3D) supramolecular architecture, which comprises two types of nanocage building units with different connectivity, using the solvent-assisted coordination-driven assembly approach. The mechanism of this supramolecular assembly process was investigated by electrospray ionization mass spectrometry (ESI-MS) studies, which identified for the first time the formation of a nanocage dimer intermediate during the assembly process. The assembly of discrete nanocages into a 3D supramolecular architecture led to remarkable enhancement of stability and gas adsorption properties.

Identifiers

PMID31367319
PMCPMC6624976

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.