ArticleChemical science2019
Ligand and counteranion enabled regiodivergent C-H bond functionalization of naphthols with α-aryl-α-diazoesters.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Heterogeneous Rhodium Single-Atom-Site Catalyst Enables Chemoselective Carbene N-H Bond Insertion.Journal of the American Chemical Society · 2024Article
- CspChemical science · 2024Review
- Theoretical Study on the Copper-CatalyzedMolecules (Basel, Switzerland) · 2023Article
- Overcoming O-H Insertion toACS central science · 2022Article
- Rhodium-Catalyzed C-H Methylation and Alkylation Reactions by Carbene-Transfer Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Multi C-H Functionalization Reactions of Carbazole Heterocycles via Gold-Catalyzed Carbene Transfer Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Metal-free tandem carbene N-H insertions and C-C bond cleavages.Chemical science · 2020Article
- Regioselective Arene C-H Alkylation Enabled by Organic Photoredox Catalysis.Angewandte Chemie (International ed. in English) · 2020Article
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Here, an unprecedented ligand and counteranion-controlled and site-selectivity switchable direct C-H bond functionalization of unprotected naphthols with α-aryl-α-diazoesters was developed. In this transformation, site selectivities are realized by turning on/off the coordination between metal complexes and hydroxy groups. The preliminary mechanism revealed that the interaction between the hydroxy group and gold catalyst plays a key role in switching the site-selectivity of gold-carbene. This protocol potentially provides a novel design for C-H bond functionalization.
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Registered trials
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