ReviewAngewandte Chemie (International ed. in English)2019
Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics.
Review in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Odd-even conductance oscillations inScience advances · 2026Article
- Long-Range Resonant Charge Transport through Open-Shell Donor-Acceptor Macromolecules.Journal of the American Chemical Society · 2025Article
- Digging through the (Statistical) Dirt: A Reproducible Method for Single-Molecule Flicker Noise Analysis.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Single-Molecule Mechanoresistivity by Intermetallic Bonding.Angewandte Chemie (International ed. in English) · 2025Article
- Toward Practical Single-Molecule/Atom Switches.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Review
- Mechanical Manipulation of Quantum Interference in Single-Molecule Junctions.Small (Weinheim an der Bergstrasse, Germany) · 2024Article
- Nuclear Magnetic Resonance Chemical Shift as a Probe for Single-Molecule Charge Transport.Angewandte Chemie (International ed. in English) · 2024Article
- Not So Innocent After All: Interfacial Chemistry Determines Charge-Transport Efficiency in Single-Molecule Junctions.Angewandte Chemie (International ed. in English) · 2023Article
- Atomically well-defined nitrogen doping for cross-plane transport through graphene heterojunctions.Chemical science · 2023Article
- Mechanical compression in cofacial porphyrin cyclophane pincers.Chemical science · 2022Article
- Tetrathiafulvalenes as anchors for building highly conductive and mechanically tunable molecular junctions.Nature communications · 2022Article
- Folding a Single-Molecule Junction.Nano letters · 2020Article
- Tuning the thermoelectrical properties of anthracene-based self-assembled monolayers.Chemical science · 2020Article
- Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics.Angewandte Chemie (International ed. in English) · 2019Review
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
Single-molecule junctions that are sensitive to compression or elongation are an emerging class of nanoelectromechanical systems (NEMS). Although the molecule-electrode interface can be engineered to impart such functionality, most studies to date rely on poorly defined interactions. We focused on this issue by synthesizing molecular wires designed to have chemically defined hemilabile contacts based on (methylthio)thiophene moieties. We measured their conductance as a function of junction size and observed conductance changes of up to two orders of magnitude as junctions were compressed and stretched. Localised interactions between weakly coordinating thienyl sulfurs and the electrodes are responsible for the observed effect and allow reversible monodentate⇄bidentate contact transitions as the junction is modulated in size. We observed an up to ≈100-fold sensitivity boost of the (methylthio)thiophene-terminated molecular wire compared with its non-hemilabile (methylthio)benzene counterpart and demonstrate a previously unexplored application of hemilabile ligands to molecular electronics.
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Registered trials
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