ArticleJournal of the American Chemical Society2019
A Radical-Polar Crossover Annulation To Access Terpenoid Motifs.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed, 49 citations in OpenAlex.
- Cascade MHAT Radical Cyclopentannulation of Skipped Enyne to Access Highly Functionalized Carbocycles.JACS Au · 2026Article
- Photochemical Ring Opening of Cyclopropyl Silyl Ethers Enables β-β Coupling, Radical-Polar Crossover and Annulation.Angewandte Chemie (International ed. in English) · 2026Article
- Natural Product Synthesis Enabled by Radical-Polar Crossover Reactions.The Journal of organic chemistry · 2025Review
- Total syntheses of (-)-macrocalyxoformins A and B and (-)-ludongnin C.Nature communications · 2024Article
- Directed Hydrogen Atom Transfer for Selective Reactions of Polyenols.Journal of the American Chemical Society · 2024Article
- Hydrogen-Atom-Transfer-Initiated Radical/Polar Crossover Annulation Cascade for Expedient Access to Complex Tetralins.Angewandte Chemie (International ed. in English) · 2023Article
- Synthesis of Pleuromutilin.Journal of the American Chemical Society · 2022Article
- A Concise Enantioselective Approach to Quassinoids.Journal of the American Chemical Society · 2022Article
- Generation of α-Boryl Radicals by HAngewandte Chemie (International ed. in English) · 2021Article
- Fe-catalyzed Fukuyama-type indole synthesis triggered by hydrogen atom transfer.Chemical science · 2021Article
- New Methods and Strategies in the Synthesis of Terpenoid Natural Products.Accounts of chemical research · 2021Review
- Stereocontrolled Radical Bicyclizations of Oxygenated Precursors Enable Short Syntheses of Oxidized Abietane Diterpenoids.Journal of the American Chemical Society · 2021Article
- Catalytic Cycloisomerization onto a Carbonyl Oxygen.Organic letters · 2020Article
- Reductive radical-polar crossover: traditional electrophiles in modern radical reactions.Chemical science · 2019Review
- Enantiospecific Entry to a Common Decalin Intermediate for the Syntheses of Highly Oxygenated Terpenoids.The Journal of organic chemistry · 2019Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
A new catalytic radical-polar crossover annulation between two unsaturated carbonyl compounds is described. The annulation proceeds under exceptionally mild conditions and provides direct and expedient access to complex terpenoid motifs. Application of this chemistry allows for synthesis of forskolin, a densely functionalized terpenoid, in 14 steps from commercially available material.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.